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One of the issues that extended spaceflight raises is the provision to the crew of a living environment not only safe but also comfortable and pleasant, two features which also enhance crew productivity. Interior design and decor are understood to gain more relevance as mission duration increases. This means that colour theory application to the actual space system configuration becomes a fundamental step. Obviously, two other relevant variables are the impact of the overall environment (e.g., illumination, structural design, other decorative techniques adopted) and the personal taste, mediated by his own experience, of the designer. The presented work started from a brief review of the general principles pertaining to colour theory, analyzing commonly accepted systems used to categorize and individualize colours with an unambiguous procedure, to exploit the theory as an exact, almost mathematical, tool.