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As a consequence of the ongoing evolution of engines, where performance is continuously improving and the use of alternative fuels is being adopted by many engine manufacturers, thermal working conditions of the exhaust valves are increasingly critical. In order to better resist the higher temperature levels of the exhaust gases, current development ranges from improvement of the cooling concept for the overall system, new materials for valve set components up to the upgrade of the exhaust manifold material. Change in the design of several valvetrain components due to the increased thermal loads is a logical consequence of this technical evolution process. Hollow exhaust valves filled with Sodium (Na) are a known technology that is widely used in passenger car engines to improve thermal behavior and to avoid the need to change to expensive materials (Ni-base alloys).