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Developing ultra thin wall ceramic substrates is necessary to meet stricter emissions regulations, in part because substrate cell walls need to be thinner in order to improve warm-up and light-off characteristics and lower exhaust system backpressure. However, the thinner the cell wall becomes, the poorer the mechanical and thermal characteristics of the substrate. Furthermore, the conditions under which the ultra thin wall substrates are used are becoming more severe. Therefore both the mechanical and thermal characteristics are becoming important parameters in the design of advanced converter systems. Whereas square cells are used world-wide in conjunction with oxidation and/or three-way catalysts, hexagonal cells, with features promoting a homogeneous catalyst coating layer, have found limited use as a NOx absorber due to its enhanced sulfur desorption capability.

Development of the ultra thin wall ceramic catalytic substrate is necessary to meet increasingly strict emissions regulations. The cell walls need to be thinner in order to improve the warm-up characteristics related to the reduction of emissions and to lower the back pressure. However, the thinner the wall thickness, the smaller the mechanical strength of the substrate becomes. For substrates with 2.5mil wall thickness, we densified a conventional material with 35% porosity to less than 30%[1] to improve erosion resistance. Furthermore, for substrates less than 2.5mil wall thickness, a denser material and strengthened end surface is necessary to protect against erosion. In addition to that, we think that a reinforced periphery is necessary for isostatic strength. In this paper, we evaluated the effect of a densified material, strengthened end surface, and a reinforced periphery.