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Technical Paper

A Review of Solid Materials as Alternative Ammonia Sources for Lean NOx Reduction with SCR

2009-04-20
2009-01-0907
The need for improved emissions control in lean exhaust to meet tightening, world-wide NOx emissions standards has led to the development of selective catalytic reduction of NOx with ammonia as a major technology for emissions control. Current systems are being designed to use a solution of urea (32.5 wt %) dissolved in water or Diesel Exhaust Fluid (DEF) as the ammonia source. While DEF or AdBlue® is widely used as a source of ammonia, it has a number of issues at low temperatures, including freezing below −12 °C, solid deposit formation in the exhaust, and difficulties in dosing at exhaust temperatures below 200 °C. Additionally creating a uniform ammonia concentration can be problematic, complicating exhaust packaging and usually requiring a discrete mixer.
Technical Paper

The Role of Ceria in Automotive Exhaust Catalysis and OBD-II Catalyst Monitoring

1993-03-01
931034
Ceria has become an increasingly important component in automotive exhaust catalysts over the past decade. Recently, with the proposal that measurements of oxygen storage be used for the on-board evaluation of catalyst performance for both low emission vehicles (LEV) and non-LEV vehicles, understanding the role of ceria and its deterioration with catalyst aging has become even more important. It is well established that ceria in an alumina support promotes oxygen storage/release by automotive catalysts under cycled air/fuel conditions, which in turn promotes the catalyst's conversion performance under those conditions. Another benefit of ceria is its enhancement of the catalytic activity for other reactions, such as the water-gas shift reaction under rich conditions. In addition, ceria may help catalyst durability by promoting precious metal dispersion and playing some role as a stabilizer of the support.
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