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To allow the HCCI vehicles to enter the market in the future, it is important to investigate the combustion deviations and operational range differences between the same research octane number fuels. In this paper, eighteen kinds of two hydrocarbon blended fuels, which were composed of n-heptane and another hydrocarbon, such as iso-octane, diisobutylene, 4-methyl-1-pentene, toluene or cyclopentane, were evaluated. Those fuels were blended to have the same research octane numbers of 75, 80, 85 and 90 by changing the blending volume ratio of n-heptane and counterpart hydrocarbon. Intake air was supercharged to 155 kPa abs and its temperature was kept at 58 °C. The HCCI engine was operated at 1000 rpm. Neither hot EGR, nor any other combustion stratification system was utilized in order to investigate the purely hydrocarbon effects on HCCI combustion.

It was reported that n-heptane and toluene blended fuels (NTL series fuels) showed the dual phase high temperature heat release (DP-HTHR) combustion in a previous SAE paper [1]. DP-HTHR has the potential to enlarge the engine operational range to high load conditions and lower the engine combustion noise. Further research has been reported in this paper. Initial interests were in the combustion characteristics of a second “bump” in the high temperature heat release (2nd HTHR) in DP-HTHR, since this kind of two-stage combustion appears, when CO oxidation radically occurs over the 1450K temperature range.

The chemical composition of marketed gasoline varies depending on the crude oil, refinery processes of oil refineries, and season. The combustion characteristics of HCCI engines are very sensitive to the fuel composition, and a fuel standard for HCCI is needed for HCCI vehicles to be commercially viable. In this paper, the effects of the structure of the fuel components on auto-ignition characteristics and HCCI engine performance were investigated. The engine employed in the experiments is a research, single cylinder HCCI engine with a compression ratio of 14.7. The intake manifold was equipped with a heater attachment allowing control of the intake air temperature up to 150 °C at 2000 rpm. Thirteen kinds of hydrocarbons, 4 kinds of paraffins, 3kinds of naphthenes, and 6 kinds of aromatics, were chosen for the investigation, and 20vol% of each of the pure hydrocarbons was blended with the 80 vol% of PFR50 fuel.

It is known that the regular gasoline and primary reference fuel (PRF), that have the same research octane number, show the different HCCI engine performance, because of the different phasing and heating value of low temperature heat release. This means that the research octane number is not an “all-round” auto-ignition index, and another index must be developed to evaluate the HCCI combustion characteristics. In this paper, eleven pure hydrocarbon components were blended into twenty three different kinds of model fuels (surrogate fuels), labeled BASE, MC01-MC11 and K01-K11, and the HCCI engine tests were performed under five different intake air temperature conditions to change the auto-ignition characteristic of each hydrocarbon component. As HCCI combustion can be described as a lean and slow gasoline knocking phenomenon, an analysis of HCCI combustion data gives us much more important knowledge of gasoline knocking phenomenon.

An HCCI combustion has a low temperature heat release (LTHR) and a high temperature heat release (HTHR). During the LTHR period, fuel chemicals break down into radicals and small hydrocarbons, and they assist an initial reaction of HTHR. This is an important role of LTHR. On the contrary, LTHR has a negative aspect. In general, a heating value of LTHR changes depending on HCCI engine load due to the difference of the injected fuel quantity. The heating value of LTHR is low under low load condition, and the heating value of LTHR is high under high load condition. This leads to the changes of the starting crank angle of HTHR against engine load and it is a nuisance problem for the control of HCCI engine operation. Therefore, a fuel which exhibits the constant LTHR phasing against engine load would be preferable.

A supercharged 4-cylinder engine was introduced to evaluate how fuel properties affect engine combustion and performance in homogeneous charge compression ignition (HCCI) operation. In this study, choosing from 12 hydrocarbon constituents, model fuels were mixed to have the same distillation but different octane numbers (RON=70, 80, 92). For each fuel, RON distribution against distillation is same to keep the same octane number in cylinder vapor during the air-fuel compression process. To confirm the appropriateness of model fuels and test procedures, regular gasoline (RON=90) was also included. From the combustion analysis it was clear that the low temperature heat release depends on fuel characteristics. RON92 fuel has a small low temperature heat release, and a high temperature heat release combusts slowly.

The HCCI engine offers the potential of low NOx emissions combined with diesel engine like high efficiency, however HCCI operation is restricted to low engine speeds and torques constrained by narrow noise (HCCI knocking) and misfiring limits. Gasoline like fuel vaporizes and mixes with air, but the mixture may auto-ignite at the same time, leading to heavy HCCI knocking. Retarding the CA50 (the crank angle of the 50% burn) is well known as a method to slow the maximum pressure rise rate and reduce HCCI knocking. The CA50 can be controlled by the fuel composition, for example, di-methyl ether (DME), which is easily synthesized from natural gas, has strong low temperature heat release (LTHR) characteristics and ethanol generates strong LTHR inhibitor effects. The utilization of DME-ethanol binary blended fuels has the potential to broaden the HCCI engine load-speed range.

To evaluate the relation between the intake air temperature (Tair-in), low temperature heat release (LTHR) and high temperature heat release (HTHR), a supercharged 4-cylinder engine with intake air heating, high compression pistons and a pressure transducer in each cylinder was introduced Eleven pure hydrocarbon components were blended into 23 different model fuels, labeled BASE MC01-MC11, and K01-K11. BASE is a mixture of equal proportion of each of the 11 pure hydrocarbons. The difference between MC series and K series fuels is in the amount of pure hydrocarbon added to the BASE: 6.5vol% for MC series fuels and 17.5vol% for K series fuels. Engine tests were performed with BASE and MC01-MC11 fuels at Tair-in=50°C (IMEP 530kPa), 80°C (IMEP 420kPa), and 100°C (IMEP 380kPa).

Low temperature heat release (LTHR) in HCCI combustion changes according to fuel chemical composition and engine test conditions. In this study 11 pure hydrocarbon components were blended into 12 different model fuels to evaluate the effects of fuel composition on LTHR heating value, LTHR CA50 (crank angle at 50% completion of LTHR), high temperature heat release (HTHR), and engine performance. From the heat release analysis of the test data from a supercharged 4-cylinder engine, it was determined that the HTHR CA50 (crank angle at 50% completion of HTHR) was strongly indicative of combustion stability and maximum rate of pressure rise. Moreover, the functional dependence of HTHR CA50 on LTHR heating value and LTHR CA50 was quantified. Test fuels denoted MD05, Base, MC05 and MX05 were prepared by adding 5.2vol%, 9.3vol%, 15.0vol%, and 18.2vol% of n-hexane, respectively, to a blend of 10 pure hydrocarbons.