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Emission of carbon dioxide from mobile sources seriously concerned to solve greenhouse effect and high price of gasoline in some countries have resulted in the development of lean-burn concept engine. In spite of many studies on the lean deNOx catalyst, we have no clear solution to obtain high fuel economy and high efficiency of NOx conversion in lean-burn application. This paper describes applicability and problems of NOx adsorber system to partial lean-burn vehicle, the development of three-way catalyst with improvement of washcoat technology based on three-way catalyst used for gasoline application, and comparison test results of evaluations is synthesized gas activity test, Federal Test Procedure (FTP) test, etc. This study shows improved three-way catalysts in partial lean- burn vehicle have max. 89% of NOx conversion in FTP without adding rich spike and regeneration functions to engine management system.

We developed new single coated Pd/Rh three-way catalysts (TWC). Several Pd/Rh single layered catalysts were prepared by changing the precious metal (PM) fixation method and adding new base metal oxides (BMO). These samples were compared with double-coated catalyst by using model gas activity test, BET test, XRD test and vehicle emission test. It is found that the performance of the single coated catalyst is as good as that of commercialized double-coated catalyst. The oxygen storage capacity of the single coated catalyst is better than that of double-coated catalyst. Moreover, manufacturing the single coated catalyst enables us to eliminate the unnecessary coating process which is essential to the conventional one. Our test results demonstrate that the developed catalyst has sufficient activity and durability of OSC to meet emission and OBD-II regulations.

It is well known that the EHC (Electrically Heated Catalyst) is very effective for the reduction of cold-start hydrocarbon emissions. To optimize EHC applications for LEVI (Low Emission Vehicle) and ULEV (Ultra Low Emission Vehicle) standards, the effect of heating and secondary air injection on the emission purification efficiency in FTP (Federal Test Procedure) were evaluated with three different EHC system configurations. The exhaust manifold location EHC system in which the EHC with a light-off catalyst is installed near the exhaust manifold, yields 0.038g/mile of THC (Total Hydrocarbon emissions) when the test was performed according to the FFP with an engine-aged condition equivalent to 50,000miles. Therefore, the ULEV standards could be achieved through the system. A new battery system for the EHC and a single battery system for vehicle application were evaluated. Evaluation of the Ni-MH battery for EHC system is included.

This paper discusses the effect of poisons originated from the engine oil and fuel on the catalytic activity of palladium based close coupled catalysts. The performances of seven aged catalysts were analyzed by synthesized gas activity tests. The effects of thermal deactivation of the catalyst were investigated by BET surface area and X-ray diffraction tests. To show the poisoning effects along the exhaust stream, the additives of oil and fuel were quantified by ICP spectrometry and x-ray flouresences (XRF). SEM-EPMA analysis were also performed to determine the distribution of poisons in the washcoat. The contribution of poisoning to the overall deactivation process could than be estimated by comparing the results before and after leaching the poisonous elements with a weak acid solution. Test results show the activity of the palladium based catalysts can be severely deteriorated by poisons.