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The diesel oxidation catalysts (DOC) having high purification performance to the exhaust gas at low temperatures were investigated. In this paper two main technological improvements from conventional DOC are shown. First is forming Pt/Pd composite particles in order to suppress sintering of precious metal under high thermal aging condition. This generating Pt/Pd composite and the effect were exemplified by TEM-EDS and XRD analysis. Second is adjusting electric charge of Pt/Pd surface to reduce interaction between Pt/Pd and carbon monoxide (CO) by modifying the support material components. Adjusting electric charge of Pt/Pd surface by applying new support material could cancel CO poisoning at Pt/Pd surface. Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) studies suggested that improved support material is more suitable for CO oxidation at a low temperature based on the concept.

Previously air-fuel ratio control using a λ O2 sensor had two problems which resulted from the binary output characteristics: (1) Insufficient convergence performance after A/F disturbance, resulting in worsening of emissions in transient states, and (2) A narrow A/F control range, resulting in worsening of emissions due to mean A/F shift in the front A/F. However, we have executed a paradigm shift to mean A/F control focused on the O2 storage ability of the catalyst and on the conversion characteristics, and carried out the following improvements. (1) Using a catalyst O2 storage model, we analyzed the interaction among front A/F feedback, O2 storage behavior, the rear. O2 signal, and emissions. Based on the results of this analysis, we designed an optimal O2 storage capacity (OSC) using a new catalyst with improved O2 storage ability, and verified that the first problem was resolved. (2) Previously, it was difficult to design front λ O2 control due to its strong non-linearity.