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The present contribution combines the consideration of the chemical reaction activity of the end gas and engine operating conditions to predict the onset of knock and associated performance in a spark ignition engine fuelled with methane. A two-zone predictive combustion model was developed based on an estimate of the effective duration of the combustion period and the mass burning rate for any set of operating conditions. The unburned end gas preignition chemical reaction activity is described by a detailed chemical reaction kinetic scheme for methane and air. The variation with time of the value of a formulated dimensionless knock parameter based on the value of the cumulative energy released due to preignition reaction activity of the end gas per unit volume relative to the total energy release per unit cylinder swept volume is calculated It is shown that whenever knocking is encountered, the value of builds up to a sufficiently high value that exceeds a critical value.

A two-zone predictive model for the performance of a spark ignited gas engine is described. In this model, an effective mass burning rate and energy release pattern based on an estimate of the combustion duration are developed. For any given engine and set of operating conditions the pressure-time and temperatures-time histories, and hence performance parameters such as indicated power output, peak pressure, optimum spark timing, etc. are predicted. Through monitoring the chemical reaction activity, while employing detailed chemical kinetics of the end gas within the unburnt zone, the incidence of autoignition and knock can also be predicted. A dimensionless knock criterion that compares the specific energy release due to end gas preignition reaction activity to the specific energy release due to combustion of the fuel is developed and used to test for the incidence of knock and its severity.