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Technical Paper

Durability of Ceramic Catalytic Converters for Motorcycles

1995-09-01
951768
Motorcycle exhaust emission standards throughout the world are becoming more stringent. Emission control systems utilizing the catalytic converter are already in production in Taiwan for 2-stroke engine motorcycles. Catalysts designed for 2-stroke engines encounter a more severe exhaust environment than do those designed for 4-stroke engines. The two aspects of increased severity are the higher temperatures and higher stresses due to engine vibrations. Precious metal catalysts have been designed to operate in the thermal environment of 2-stroke engines and such catalysts have been successfully applied to both metal and ceramic substrates. However, until now, only the metal substrate catalysts have been utilized in motorcycle application. Ceramic based catalysts have not been considered because the mounting material that holds the catalyst substrate in place did not have enough durability to withstand the thermal/vibrational forces encountered in 2-stroke engine exhaust.
Technical Paper

Three-Way Conversion Catalysts: Effect of Closed-Loop Feed-Back Control and Other Parameters on Catalyst Efficiency

1980-02-01
800462
Monolithic three-way conversion (TWC) catalysts, at different precious metal concentrations, were aged on an engine dynamometer with fuel doped with lead (0.012 g Pb/gal). These catalysts were subsequently evaluated on an engine dynamometer to examine the effects of air/fuel ratio set point, temperature, and air/fuel ratio amplitude and frequency on the conversion efficiencies for NOx CO and HC. In all evaluations, as the precious metal concentration increased from 5 g/ft3 to 40 g/ft3, the NOx CO and HC conversions increased. Also, the smallest effect of precious metal loading on catalyst efficiency was found at the smallest air/fuel amplitude (±0.3 A/F). The highest overall conversions of NOx CO and HC were obtained at the stoichiometric control point for perturbations of ±0.3 A/F amplitude. Therefore, it appears that a considerable savings in precious metals can be realized if the A/F amplitude of a closed-loop feed-back control system is small (±0.3 A/F).
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