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Knocking is the main obstacle of increasing compression ratio to improve the thermal efficiency of gasoline engines. In this paper, the concept of stratified stoichiometric mixture (SSM) was proposed to suppress knocking in gasoline engines. The rich mixture near the spark plug increases the speed of the flame propagation and the lean mixture in the end gas suppresses the auto ignition. The overall air/fuel ratio keeps stoichiometric to solve the emission problem using three way catalysts (TWC). Moreover, both the rich zone and lean zone lead to soot free combustion due to homogeneous mixture. The effect on the knocking of homogeneous and stratified mixture was studied in a direct injection spark ignition (DISI) engine using numerical simulation and experimental investigation respectively.

A 1-Dimensional (1-D) model of fluid dynamic and chemistry kinetics following hot spot auto-ignition has been developed to simulate the process from auto-ignition to pressure wave propagation. The role of wall effect on the physical-chemical interaction process is numerically studied. A pressure wave is generated after hot spot auto-ignition and gradually damped as it propagates. The reflection of the wall forms a reflected pressure wave with twice the amplitude of the incident wave near the wall. The superposition of the reflected and forward pressure waves reinforces the intensity of the initial pressure wave. Wall effect is determined by the distance between the hot spot center and the cylinder wall. Hot spot auto-ignition near the wall easily initiates detonation under high-temperature and high-pressure conditions because pressure wave reflection couples with chemical reactions and propagates in the mixture with high reactivity.

Super knock which occurs in highly boosted spark ignition engines in low speed pre-ignition regime can lead to severe engine damage. However, super knock occurs occasionally, it is difficult to clearly identify the causes. The widely accepted assumption for the cause of this phenomenon is oil intrusion. Most of oils have been proved to have higher cetane number than n-heptane dose, indicating that the intruded oil is very liable to auto-ignition in a boosted engine. Although there have been reported the type of base oil and additive has significant effect on pre-ignition frequency, the oil induced super knock is still so far not supported by any direct evidence. This paper presents the effect of direct oil intrusion into cylinder on super knock. The experiment was carried out in a single cylinder engine. The diluted oil by gasoline with different ratio was directly injected into cylinder using a modified single-hole injector with 4MPa injection pressure.