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Technical Paper

Influence of Fuel Volatility on Emissions and Combustion in a Direct Injection Spark Ignition Engine

1998-10-19
982701
The purpose of this work was to investigate the influence of fuel parameters on emissions, combustion and cycle to cycle IMEP variations in a single cylinder version of a commercial direct injection stratified charge (DISC) spark ignition engine. The emission measurements employed both conventional emission measurement equipment as well as on-line gas chromatography/mass spectrometry (GC/MS). Four different fuels were compared in the study. The fuel parameters that were studied were distillation range and MTBE (Methyl Tert Buthyl Ether) content. A European certification gasoline fuel was used as a reference. The three other fuels contained 10% MTBE. The measurements were performed at a low engine speed and at a low, constant load. The engine was operated in stratified mode. The start of injection was altered 15 crankangle degrees before and after series calibration with fixed ignition timing in order to vary mixture preparation time.
Technical Paper

Solid-State 1H NMR Spin-Lattice Relaxation in Combustion Chamber Deposits from a Gasoline Direct Injection Engine

2004-03-08
2004-01-0042
Combustion chamber deposits from a gasoline direct injection stratified charge SI engine were analyzed using solid-state 1H inverse recovery NMR spectroscopy, before and after thermal desorption (TD). The engine was run with a typical European base fuel, containing 9.8% MTBE. Before TD, solid-state 1H NMR showed two broad peaks representing aliphatics and aromatics. The results showed that T1 (the relaxation time) of the aliphatics was significantly longer than T1 of the aromatics in the deposits. Deposits taken from the piston bowl, with the lowest volatility content, showed the shortest T1. In comparison, piston squish and piston bowl deposits, with higher volatility content showed a longer T1. After TD, T1 of the aliphatics was shorter than the corresponding T1 of the aromatics. A decreasing T1 of aliphatics may be used for following a transition from a liquid (engine oil), via a semi-solid deposit to a solid carbon backbone.
Technical Paper

Influence of Fuel Parameters on Deposit Formation and Emissions in a Direct Injection Stratified Charge SI Engine

2001-05-07
2001-01-2028
This work investigates the influence of fuel parameters on deposit formation and emissions in a four-cylinder direct injection stratified charge (DISC) SI engine. The engine tested is a commercial DISC engine with a wall-guided combustion system. The combustion chamber deposits (CCDs) were analyzed with gas chromatography / mass spectrometry as well as thickness and mass measurements. Intake valve deposits (IVDs) were analyzed for mass, while internal injector deposits were evaluated using spray photography. The CCD build-up was obtained with the CEC1 F-020-A-98 performance test for evaluation of the influence of fuels and additives on IVDs and CCDs in port fuel injected SI engines. The 60 h test is designed to simulate city driving. Four fuels were compared in the study: a base gasoline, with and without a fuel additive, a specially blended high volatility gasoline, and a fuel representing the worst case of European gasolines; neither of the latter two had additives.
Technical Paper

Characterization of Combustion Chamber Deposits from a Gasoline Direct Injection SI Engine

2003-03-03
2003-01-0546
Combustion chamber deposits (CCDs) from a gasoline direct injection stratified charge SI engine were analysed. The engine was run with two fuels: a typical European base fuel, containing 9.8% MTBE, and a low volatility worst case fuel. The worst case fuel is a standardized European fuel, CEC RF 86-A-96, prone to form deposits. It contains high amounts of aromatics and olefins but no MTBE. The deposits were analyzed in several ways; thermal desorption followed by gravimetric analysis, fast neutron activation analysis and solid-state 13C nuclear magnetic resonance spectroscopy. Up to 50% of the deposits, formed inside the GDI engine, consist of volatiles. The composition of the deposits is strongly related to the composition of the engine oil. The fraction of volatiles in the deposits decreased in the order: cylinder head, piston squish surface and piston bowl. The deposits from the piston squish surface contained the highest fraction of oxygen, about 30 %.
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