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The purpose of this work was to investigate the influence of fuel parameters on emissions, combustion and cycle to cycle IMEP variations in a single cylinder version of a commercial direct injection stratified charge (DISC) spark ignition engine. The emission measurements employed both conventional emission measurement equipment as well as on-line gas chromatography/mass spectrometry (GC/MS). Four different fuels were compared in the study. The fuel parameters that were studied were distillation range and MTBE (Methyl Tert Buthyl Ether) content. A European certification gasoline fuel was used as a reference. The three other fuels contained 10% MTBE. The measurements were performed at a low engine speed and at a low, constant load. The engine was operated in stratified mode. The start of injection was altered 15 crankangle degrees before and after series calibration with fixed ignition timing in order to vary mixture preparation time.

The exhaust emissions from a gasoline direct injection (GDI) engine were sampled using the bottle in bag method and analysed using gas chromatography/mass spectrometry (GC/MS). The GDI engine was run two times using two specially mixed fuels: a typical European base fuel containing additive and a fuel representing worst-case of European gasolines, which is a standardized European fuel, CEC RF 86-A-96, prone to form deposits. The engine was run 60 h for each fuel simulating city driving. Emissions were taken at times 0 h (at the start of the engine), 30 h and 60 h. As a complement, particulate emissions derived from the additized base fuel were sampled on a glass filter during the first 30 h engine run. The extractable organics contained in the filter were analysed using GC/MS analysis. Generally, the emissions were dominated by gasoline components with similar relations as in the gasoline.

Combustion products, exhaust emissions and engine exhaust deposits formed on thermocouples, positioned after the heat exchanger of an engine power plant, were analyzed chemically. The engine was a lean burn 18W28SG 50 Hz (Wärtsilä NSD, Trollhättan Sweden) fuelled with natural gas equipped with a catalyst (Süd-Chemie NMHC catalyst). The exhaust emissions were sampled using the off-line bottle-in-bag (BiB) method and were analyzed by gas chromatography/flame ionization (GC/FID). Heavier organic compounds and aldehydes were separately collected using adsorption cartridges. The combustion products measured in the emissions were mainly ethene, propene and formaldehyde indicating normal combustion of the fuel in the engine. Organics contained in the engine exhaust deposits were extracted using three different extraction methods: thermal desorption (TD), liquid extraction (LE) and super critical fluid extraction (SFE). The extracts were analyzed by GC/MS.