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Because of domestic production from renewable sources and their clean burning nature, alcohols, especially ethanol, have seen growing use as a blending agent and replacement for basic hydrocarbons in gasoline. The increasing use of alcohol in fuels raises questions on the safety of these fuels under certain non-operational situations. Modern vehicles use evaporative emission control systems to minimize environmental emissions of fuel. These systems must be relatively leak-free to function properly and are self-diagnosed by the vehicle On-Board Diagnostic system. When service is required, the service leak testing procedures may involve forcing test gases into the “evap” system and also exposure of the fuel vapors normally contained in the system to atmosphere. Previous work has discussed the hazards involved when performing shop leak testing activities for vehicles fuelled with conventional hydrocarbon gasoline [1, 2].