Search Results

Exhaust gas from the diesel engine contains particulate matter (PM) of soot that affects human health and the environment. For the reduction of the emission of the PM, the diesel particulate filter (DPF) is placed in the exhaust system. The pressure drops increases with the PM deposit quantity in the DPF, which results in the burden of the engine. Therefore, the PM should be removed regularly by oxidation process called regeneration. Consumption of fuel is improved by optimizing the timing of regeneration. However, it is difficult to visualize the behavior of PM trapping and oxidation. We have proposed a series of models from PM deposition to the oxidation process in the DPF. In this study, the behavior of deposition and oxidation of PM in the DPF with a catalyst are calculated. The numerical calculations are performed to estimate PM deposition-oxidation process within the DPF. The results are obtained using the simplified model constructed in this study.

This paper presents the numerical simulation method to predict the deactivation process of three-way catalytic converters. Three-way catalytic converter's deactivation typically results from thermal and chemical mechanisms. The major factor of thermal deactivation is the sintering of noble metal particles, which is known to depend on the ageing temperature and the oxygen concentration in the exhaust gas. The chemical deactivation is mainly caused by the poisoning, which has two effects on the catalyst deactivation. One effect is the loss of the catalyst activity, which is expressed by reduced frequency factors of reaction rates. Another effect is the suppression of the noble metal sintering. Poison deposits prevent the noble metal particles from moving in the washcoat, assisted by the reduced thermal loading of reaction heats, which is caused by the loss of the catalyst activity. Modeling these deactivation factors, we propose the rate expression of noble metal sintering.