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Modeling of unburned hydrocarbon oxidation in an SI engine was performed in engine condition using modified one-step oxidation model. The new one-step equation was developed by modifying the Arrhenius reaction rate coefficients of the conventional one-step model. The modified model was well matched with the results of detailed chemical reaction mechanism in terms of 90 % oxidation time of the fuel. In this modification, the effect of pressure and intermediate species in the burnt gas on the oxidation rate investigated and included in developed one-step model. The effect of pressure was also investigated and included as an additional multiplying factor in the reaction equation. To simulate the oxidation process of piston crevice hydrocarbons, a computational mesh was constructed with fine mesh density at the piston crevice region and the number of cell layers in cylinder was controlled according to the motion of piston.

The liquid fuel film on the cylinder liner is believed to be a major source of engine-out hydrocarbon emissions in SI engines, especially during cold start and warm-up period. Quantifying the liquid fuel film on the cylinder liner is essential to understand the engine-out hydrocarbon emissions formation in SI engines. In this research, two-dimensional visualization was carried out to quantify liquid fuel film on the quartz cylinder liner in an SI engine test rig. In addition, comparing visualization results with the trend of hydrocarbon emissions in this engine, the effect of cylinder wall-wetting during a simulated cold start and warmed-up condition was investigated with the engine experiment. The visualization was based on laser-induced fluorescence and total reflection. Using a quartz liner and a special lens, only the liquid fuel on the liner was visualized.

The liquid fuel film on the cylinder liner is believed to be a major source of engine-out hydrocarbon emissions in SI engines, especially during cold start and warm-up period. Quantifying the liquid fuel film on the cylinder liner is essential to understand the engine-out hydrocarbon emissions formation in SI engines. In this work, the fuel film formation model was developed to investigate the distribution of wall fuel film on the cylinder wall of an SI engine. By integrating the continuity, momentum, and energy equations along the direction of fuel film thickness the simulation of the fuel film formation was carried out in the test rig. Spray impingement and fuel film models were incorporated into the computational fluid dynamics code, STAR-CD to calculate fuel film thickness and distribution of fuel film on the cylinder wall. With a laser-induced fluorescence method, the two-dimensional visualization of liquid fuel films was carried out to validate the simulation results.

The soot emission in direct-injection spark-ignition engines under various operating conditions was numerically investigated in the present study. A detailed soot model was used to resolve the physical soot process that consists of polycyclic aromatics hydrocarbon (PAH) formation and soot particle dynamics. The primary propagating flame in partially-premixed field was described by G-equation model, and the concentrations of burned species as well as PAH behind of the flame front were determined from the laminar flamelet library that incorporates the PAH chemical mechanism. The particle dynamics in post-flame region include nucleation, surface growth, coagulation, and oxidation were modeled by method of moments. To improve the model predictability, a gasoline surrogate model was proposed to match the real fuel properties, and the input of droplet size distribution of fuel spray was obtained from Phase-Doppler Particle Analyzer.

This paper provides an overview of spark-ignition engine unburned hydrocarbon emissions mechanisms, and then uses this framework to relate measured engine-out hydrocarbon emission levels to the processes within the engine from which they result. Typically, spark-ignition engine-out HC levels are 1.5 to 2 percent of the gasoline fuel flow into the engine; about half this amount is unburned fuel and half is partially reacted fuel components. The different mechanisms by which hydrocarbons in the gasoline escape burning during the normal engine combustion process are described and approximately quantified. The in-cylinder oxidation of these HC during the expansion and exhaust processes, the fraction which exit the cylinder, and the fraction oxidized in the exhaust port and manifold are also estimated.

To understand the effects of crevices on the engine-out hydrocarbon emissions, a series of engine experiments was carried out with different piston crevice volumes and with simulated head gasket crevices. The engine-out HC level was found to be modestly sensitive to the piston crevice size in both the warmed-up and the cold engines, but more sensitive to the crevice volume in the head gasket region. A substantial decrease in HC in the cold-to-warm-up engine transition was observed and is attributed mostly to the change in port oxidation.

In this work, the operating strategy for diesel injection methods and a way to control the exhaust gas recirculation (EGR) rate under dual-fuel PCCI combustion with an appropriate ratio of low-reactivity fuel (propane) to achieve high combustion stability and low emissions is introduced. The standards of combustion stability were carbon monoxide (CO) emissions below 5,000 ppm and a CoV of the indicated mean effective pressure (IMEP) below 5 %. Additionally, the NOx emissions was controlled to not exceed 50 ppm, which is the standard of conventional diesel combustion, and PM emissions was kept below 0.2 FSN, which is a tenth of the conventional diesel value without a diesel particulate filter (DPF). The operating condition was a low speed and load condition (1,500 rpm/ near gIMEP of 0.55 MPa).