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In this paper some results relative to tests performed on road with a Fiat Panda Bipower, (CNG and gasoline powered), and a New Panda Twin Air with auto Start & Stop system, are presented. Gaseous emissions are measured with Portable Emission Measurement Systems (PEMS) on two different urban routes, in terms of traffic and slope characteristics during in use experiments. PEMS testing offers an easy and efficient way to evaluate the vehicle emissions over a huge variety of conditions and provides us a direct way to study the in-use emissions of combustion engines, when you want to verify the effect of the traffic and of a particular device on fuel economy and emissions reduction. Moreover now PEMS performances are very comparable to those obtained by standard laboratory instrumentation systems.