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The objective of this study was to mathematically model several proposed vehicle glazing materials using derived force-deflection characteristics, validate the models' dynamic behavior, and use the resulting glazing models in simulations of occupant dynamics during vehicle rollover. Simulations were performed with the three-dimensional, multibody dynamics program, the Articulated Total Body (ATB) model. The contact characteristics of side windows of tempered glass; polymethyl methacrylimide, also referred to as PMMI; and polycarbonate; as well as windshields from Ford Tempos and Jeeps, were developed from headform impact tests. These characteristics were first validated by performing simulations of the headform impact tests, and were then included in rollover simulations. Previously validated simulations of belted driver and unbelted passenger dynamics during an actual rollover accident were used as the baseline simulations.