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The effect of different fuel parameters on emissions is difficult to understand, the response depending upon different engine technologies. In addition the isolation of some of the fuel variables is often very hard. The present paper discusses the main results obtained testing a matrix of 14 fuels designed for obtain large variations of cetane number, sulphur and aromatic contents of Diesel oil. The aromatic structure of fuels and its effect on particulate emissions was also investigated. A linear regression analysis was performed in order to isolate the main controlling factors on particulate emissions. Finally the influence of aromatic contents of fuel on unregulated emissions was also assessed.

Cetane number, sulphur content and aromatic structure of Automotive Diesel Oil (ADO) were changed to assess their influence on emissions of light duty direct injection Diesel engine. The detailed chemical analysis of particulate soluble fraction allows to quantify the P.A.Hs emission. In addition also the aldehydes and volatile organic compounds were measured in the gaseous phase. The sulphur content of the fuel and its aromatic structure strongly influence particulate emission. The insoluble fraction of the particulate rises with an increase of the high sulphur content ADOs with about the same back end volatility. Unburned P.A.Hs control P.A.Hs emission at the part loads typical of normalized schedules for emission testing of light duty vehicles in Europe. Finally the level of emissions of benzene and 1-3 butadiene is comparable to the total P.A.Hs emission.