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An on-board version of a fast response chemiluminsescence analyzer with a 3-millisecond response time enables the recording of high temporal resolution transient NOx emissions during cold start and pull-away, gear changes, speed bumps and other real world transient conditions. Tests were initially performed on a 1.6 litre turbo GDI vehicle before comparison with a diesel vehicle. The data has been correlated with on-board engine data available from the vehicle’s electronic control unit to study the underlying causes of these short-duration events. Exhaust gas was generally sampled from downstream of the after treatment system but before the silencer (muffler) to preserve all high frequency detail and to allow accurate integration of pollutant concentration and engine exhaust mass flow.

Ammonia (NH3) is a carbon-free fuel, which could partially or completely eliminate hydrocarbon (HC) fuel demand. Using ammonia directly as a fuel has some challenges due to its low burning speed and low flammability range, which generates unstable combustion inside the combustion chamber. This study investigated the effect of two different compression ratios (CRs) of 10.5 and 12.5 on the performance of ammonia combustion by using a conventional single spark-ignition (SI) approach. It was found that at a lower CR of 10.5, the combustion was unstable even at advanced spark timing (ST) due to poor combustion characteristics of ammonia. However, increasing the CR to 12.5 improved the engine performance significantly with lower cyclic variations. In addition, this research work also observed the effect of multiple spark ignition strategies on pure ammonia combustion and compared it with the conventional SI approach for the same operating conditions.

Ammonia as a fuel suffers from a high ignition energy requirement making it hard to ignite in stoichiometric mixtures, especially with normal spark plugs. On the other hand, pre-chambers are proven to provide high ignition energy by producing multiple ignition spots in the main chamber. A pre-chamber is usually categorized as “active” if it has a dedicated fueling system, and as “passive” if it depends solely on the air- fuel mixture being introduced from the main chamber and is therefore simpler than the active type. In this study, an SI light-duty engine was tested with a conventional spark plug with fuel mixtures of gasoline and gaseous ammonia (0%, 25%, 50%, 75%, 90%, and 100% NH3). The test was then repeated with a passive pre-chamber under the same operating conditions for comparison. Moreover, the engine exhaust was fitted with a fast response analyzer to measure NOX. The use of the conventional spark plug showed stable combustion throughout the fuel mixture sweep.