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Formation of nitrogen oxides (NOx) in direct-injection premixed charge compression ignition (DI-PCCI) combustion simulated in a constant volume vessel was investigated using an ignition-combustion model that combines a stochastic mixing model with a reduced chemical reaction scheme. Several improvements were made to the model in order to predict the combustion processes in DI-PCCI. Calculations were carried out for the injection and ambient conditions equivalent to the measurements using the constant volume vessel. Analysis of the calculated results clarified the effects of mixture heterogeneity on NO concentrations and the mechanisms are discussed. The results show that the model successfully represents the experimental tendency for NO concentration when the injection conditions and ambient oxygen mole fraction are varied.

Fundamental investigation is conducted on flow and the spark-ignited combustion process of a high-speed, unsteady hydrogen jet, by experimental and theoretical approaches. Jet development and flame propagation in a constant-volume vessel were visualized by means of the shadowgraph technique. The effects of ignition timing and ignition location on the combustion process were investigated. Furthermore, a numerical simulation was performed by using incompressible-flow type computational fluid dynamics with the k-ε turbulence model and the flamelet concept. The pseudo-nozzle concept is applied to the inlet condition with a large pressure gradient. The flame propagation process is described by reference to the flame area evolution model. The results show that the pressure-history in a vessel and the flame propagation process are successfully described for experimental data. Furthermore, the flame propagation process in a jet is investigated.

A new model to describe diesel combustion process has been developed. In this model diesel combustion field is divided into two zones, premixing and combustion. Turbulent mixing process is described by the stochastic approach in each zone separately. Comparison of calculations with experimental results showed that this model can predict the entire course of heat release and nitrogen-oxide formation precisely, under wide-spread conditions. Two-dimensional flame temperature distributions in the combustion field by the two color method were compared with simulation results. Both the measured and the calculated flame temperature distributions showed good agreements with each other. In the diesel combustion process, the injected fuel mixes with air entrained inside the spray. The mixture is thus formed, and ignites at several points. Random expansion of flamelets accelerates both mixing and combustion. Following this, fairly moderate diffusion combustion proceeds.