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Aftertreatment devices are exposed to exhaust poisons from fuel, oil and coolant. Studies on fuel- and lubricant-based poisoning have been widely published. However, diesel oxidation catalyst (DOC) and catalyzed soot filter (CSF) performance after exposure to constituents of coolant is not fully understood. Exhaust gas recirculation (EGR) cooler failure can cause a coolant leak into the exhaust that can reach the exhaust aftertreatment system. Coolant contains elements that can cause deterioration of aftertreatment components. This study focuses on the poisoning effect of coolant on the performance of a DOC + CSF system. The coolant introduction simulates an engine failure such as an EGR cooler internal fracture. DOC NO oxidation, quenching and hydrocarbon (HC) slip control performance during active regenerations are evaluated after slow and after consecutive fast coolant introduction and compared to the performance before the coolant exposure.

A breakthrough catalyst technology utilizing new mixed metal oxides in conjunction with Platinum Group Metals has been developed. Stable synergies are designed into the catalyst washcoat that enable high performance and durability to be achieved at low Platinum Group Metal usage. Extensive vehicle data is reported on catalysts aged using a variety of high-temperature accelerated aging cycles. Vehicle performance at the LEV, ULEV and LEV-II levels is discussed in the context of unique calibration-catalyst interactions. Conclusions concerning further areas of improvement and future applications are also reviewed.

Catalytic Solutions, Inc. has developed a breakthrough catalyst technology utilizing new mixed metal oxides in conjunction with Platinum Group Metals. Stable synergies are designed into the catalyst washcoat that enable high three-way performance durability to be achieved at low precious metal usage. Several vehicle test cases will be reported showing how this low-PGM technology meets LEV-II and ULEV-II performance levels. Catalyst technology developments discussed in the vehicle setting will be referenced with flow reactor studies that simulate critical FTP performance features. Results of characterization studies on fresh and aged coatings will be described, and discussed in the context of vehicle aging factors.