Search Results

This paper presents a methodology for a rapid determination of biogas composition using easily detectable physical properties. As biogas is mainly composed of three constituents, it is possible to determine its composition by measuring two physical properties and using specific ternary diagrams. The first part of the work deals with the selection of two physical properties, which are easy and inexpensive to measure, from a group comprising thermal conductivity, viscosity and speed of sound. Then, in the second part, a model to express these properties in terms of ternary composition is presented. It is demonstrated that the composition of a ternary gas mixture can be determined with good precision using the above. The model is applied to specific situations such as the online determination of the lower heating value of biogas without any complicated apparatus like calorimeters or batch techniques (gas chromatographs).

Natural gas composition depends on when and where it is recovered. Variations of composition affect the performance of combustion systems and the accuracy of delivered energy in fiscal gas metering. This paper presents a methodology to determine combustion properties of natural gases (higher heating value, Wobbe index and the stoichiometric air-fuel ratio). A pseudo-gas formulation is used to determine a composition of the most influent constituents of the natural gas. The pseudo-composition is then determined by solving a nonlinear system of equations using thermal conductivity at three levels of temperature and the carbon dioxide concentration. The tested natural gases are chosen to represent typical European gases as well as to account for large variations of individual components. The error on the combustion properties is less than 0.5% for the most of the examined gases and below 1% for gases with high carbon dioxide fractions.