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The selective catalytic reduction (SCR) based on urea-water-solution is an effective technique to reduce nitrogen oxides (NOx) emitted from diesel engines. A 3D numerical computer model of the injection of urea-water-solution and their interaction with the exhaust gas flow and exhaust tubing is developed to evaluate different configurations during the development process of such a DeNOx-system. The model accounts for all relevant processes appearing from the injection point to the entrance of the SCR-catalyst: momentum interaction between gas phase and droplets evaporation and thermolysis of droplets hydrolysis of isocyanic acid in gas phase heat transfer between wall and droplets spray/wall-interaction two-component wall film including interaction with gas phase and exhaust tube The single modeling steps are verified with visualizations, patternator measurements, phase-doppler-anemometer results and temperature measurements.

The ultimate goal in the numerical simulation of automotive catalytic converters is the prediction of exhaust gas emissions as function of time for varying inlet conditions, i.e. the simulation of a driving cycle. Such a simulation must include the calculation of the transient three-dimensional temperature-field of the monolithic solid structure of the converter, which results from a complex interaction between a variety of physical and chemical processes such as the gaseous flow field through the monolith channels, the catalytic reactions, gaseous and solid heat transport, and heat transfer to the ambience. This paper will discuss the application of the newly developed CFD-code DETCHEMMONOLITH for the numerical simulation of the transient behavior of three-way catalytic converters that have a monolithic structure.