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A Computational and Experimental Study of Combustion Chamber Deposit Effects on NOx Emissions

1993-10-01
932815
The oxides of nitrogen (NOx) produced during combustion in an automobile engine play a major role in atmospheric chemistry and therefore need to be reduced by modifying vehicle engine designs and fuels of tomorrow. In a combustion chamber of a spark ignited engine, NOx is formed as atmospheric nitrogen competes with fuel molecules to couple with oxygen in the extremely hot burned gases behind the proceeding flame front (Zeldovich type) and as reactions occur directly in the combustion flame zone (“prompt” type). Since little nitrogen is present in the fuel, the fuel contribution to the overall NOx emissions is minor. Certain combustion chamber deposits have been shown to increase NOx emissions by thermally insulating the combustion chamber and taking up chamber volume, thus slightly increasing the compression ratio of the engine and raising the combustion gas temperature.
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