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Automotive brake linings are complex composite materials. Some raw materials used by manufacturers or the compounds created during the friction process might be potentially hazardous and may cause various adverse effects. Different fractions of the brake wear debris can be released during braking: i) the airborne and ii) the nonairborne. Due to the small size and minimum gravitational action, the airborne particles could be spread for long distances from a source and typically remain suspended in the air for long periods of time. Our previous research demonstrated that the airborne fraction contains considerable amounts of different nanoparticulates. On the other hand, the emitted nonairborne fraction typically settles on vehicle/brake hardware surfaces and in the vicinity of roads. The nonairborne particles are considered to be relatively large, but it was shown that nano-sized particles readily attach to them and can be released later.

Copper and copper alloys are widely used in friction materials such as brake pad formulations as one of key ingredients by providing good thermal conductivity and high temperature friction stability to achieve desired friction performance, fade and wear resistance. However, the use of copper or copper containing material is being restricted in brake pads due to environment and health concerns. Extensive works have been made to explore the copper substitutes but most of these efforts became ineffective and failed with issues either thermal fade or excessive pad/rotor wear. In this paper, friction and wear responses were examined when a metallic composite material was used as the copper substitute in NAO and Low-met brake formulations where the copper and copper alloys were added 8% and 22% respectively.

Automotive brake lining materials are complex composites consisting of numerous ingredients allowing for their optimal performance. Since regulations are increasingly limiting Cu content in brake pads and Cu exhibits extremely high thermal conductivity, graphites being excellent heat conducting materials themselves, are often considered for use as potential Cu replacement. This paper surveys the role of two types of carbons (Superior Graphite) with high thermal conductivity but different mechanical properties and morphology: the so-called i) purified flake graphite (PFG) and the ii) resilient graphitic carbon (RGC). A successful “high-end” commercial low-metallic brake pad was re-formulated (SIU Carbondale) by removing of over 20 wt. % of Cu and replacing it with a cocktail of ingredients including 15 wt. % of these two graphite types (RGC and PFG).

The brake wear contribution to the environmental pollution has been extensively discussed, with major focus on asbestos and heavy metals released to the environment. Only limited attention was paid to released organic compounds generated during friction processes, although the organic and carbonaceous components are not the minor part in brake lining formulations. Friction processes in brakes are associated with relatively high temperatures and high pressures on the friction surfaces which relates to the thermal decomposition of the organic components in friction materials and to brake lining thermal fade. Thus, this study focuses on the identification of organic compounds released from a model low metallic brake material.