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The selective catalytic reduction (SCR) of nitrogen oxides by ammonia is commonly applied as a method of exhaust aftertreatment for lean burn compression ignition (CI) engines. The catalytic reactor of an SCR system, like all catalytic emission control devices, is susceptible to partial deactivation as its operating time progresses. Long-term exposure of an SCR reactor to exhaust gas of fluctuating temperature and composition results in variations of the characteristics of its catalytically active layer. The aim of this study was to observe and investigate the variation of parameters characterizing the SCR reactor as a result of its ageing. Attention was paid to changes in ammonia storage capacity, selectivity of chemical reactions and maximum achievable NOx conversion efficiency. The experimental setup was a heavy duty (HD) Euro VI-compliant engine and its aftertreatment system (ATS). The setup was installed on a transient engine dyno instrumented with emission measurement devices.

The aim of this paper is to analyse the results of regulated and unregulated emissions and carbon dioxide (CO2) emissions of passenger cars equipped with compression-ignition engines that meet the emission Euro 6d standards. Both test vehicles featured selective catalytic reduction (SCR) systems for control of oxides of nitrogen (NOx) and one vehicle also featured a passive NOx absorber (PNA). Research was performed using the current European Union exhaust emission test methods for passenger cars (Worldwide harmonized Light vehicles Test Procedures (WLTP)). Emission testing was performed on a chassis dynamometer, within a climatic chamber, at two different ambient temperatures: 23°C (i.e. Type I test) and -7°C (known as a Type VI test - currently not required for this engine type according to EU legislative requirements).

European Union RDE (real driving emissions) legislation requires that new vehicles be subjected to emissions tests on public roads. Performing emissions testing outside a laboratory setting immediately raises the question of the impact of ambient conditions - especially temperature - on the results. In the spirit of RDE legislation, a wide range of ambient temperatures are permissible, with mathematical moderation (correction) of the results only permissible for ambient temperatures <0°C and >+30°C. Within the standard range of temperatures (0°C to +30°C), no correction for temperature is applied to emissions results and the applicable emissions limits have to be met. Given the well-known link between the thermal state of an engine and its emissions following cold start, ambient temperature can be of great importance in determining whether a vehicle meets emissions requirements during an RDE test.

Vehicular ammonia emissions are currently unregulated, even though ammonia is harmful for a variety of reasons, and the gas is classed as toxic. Ammonia emissions represent a serious threat to air quality, particularly in urban settings; an ammonia emissions limit may be introduced in future legislation. Production of ammonia within the cylinder has long been known to be very limited. However, having reached its light-off temperature, a three-way catalyst can produce substantial quantities of ammonia through various reaction pathways. Production of ammonia is symptomatic of overly reducing conditions within the three-way catalyst (TWC), and depends somewhat upon the particular precious metals used. Emission is markedly higher during periods where demand for engine power is higher, when the engine will be operating under open-loop conditions.

Diesel (compression ignition, CI) engines are increasingly exploited in light-duty vehicles, due to their high efficiency and favorable characteristics. Limited work has been performed on CI cold-start emissions at low temperatures. This paper presents a discussion and a brief literature review of diesel cold-start emissions phenomena at low ambient temperatures and the results of tests performed on two European light-duty vehicles with Euro 5 CI engines. The tests were performed on a chassis dynamometer within an advanced climate-controlled test laboratory at BOSMAL Automotive Research and Development Institute, Poland to determine the deterioration in emission of gaseous (HC, CO, NOx, CO2) and solid (PM, PN) pollutants following the EU legislative test procedure (testing at 20°C to 30°C and at -7°C, performed over the NEDC). The tests revealed appreciable increases in emissions of regulated pollutants.

Spark ignition (SI) engines are susceptible to excess emissions at low ambient temperatures. Direct injection leads to the formation of particulate matter (PM), and direct injection spark ignition (DISI) engines should show greater PM emissions at low ambient temperatures. This study compares excess emissions of gaseous and solid pollutants following cold start at a low ambient temperature and the standard test temperature. Euro 5 passenger cars were tested on a chassis dynamometer within BOSMAL's climate-controlled test chamber, according to European Union legislation (−7°C over the urban driving cycle (UDC), and at 25°C). Two vehicles were also tested over the entire New European Driving Cycle (NEDC). Emissions of regulated compounds and carbon dioxide were analyzed; particulate emissions (both mass and number) were also measured, all using standard procedures.

Direct injection gasoline engines have been gaining popularity for passenger car applications, particularly in the EU. It is well known that emissions of particulate matter are an inherent disadvantage of spark ignition engine with direct injection. Direct injection of gasoline can lead to the formation of substantial numbers of particulates, a proportion of which survive to be emitted from the vehicle's exhaust. EU legislation limits particle mass (PM) emissions; particle number (PN) is soon to be limited, although an opt-out means that dedicated filters will not be required immediately. A range of tests were conducted on a pool of Euro 5 passenger cars in BOSMAL's climate controlled emissions laboratory, using EU legislative test methodology. In addition, further measurements were performed (particle size distribution, tests at multiple ambient temperatures).

Ethanol has long been a fuel of considerable interest for use as an automotive fuel in spark ignition (SI) internal combustion engines. In recent years, concerns over oil supplies, sustainability and geopolitical factors have lead multiple jurisdictions to mandate the blending of ethanol into standard gasoline. The impact of blend ethanol content on gaseous emissions has been widely studied; particulate matter emissions have received somewhat less attention, despite these emissions being regulated in the USA. Currently, in the EU particulate matter emissions from SI engines are partially regulated - only vehicles featuring direct injection SI engines are subject to emissions limits. A range of experiments was conducted to determine the impact of fuel ethanol content on the emissions of solid pollutants from Euro 5 passenger cars.

The paper evaluates the possibility of using different biodiesel blends (mixture of diesel fuel and Fatty Acid Methyl Esters) in modern Euro 4/ Euro 5 direct-injection, common-rail, turbocharged, light-duty diesel engines. The influence of different quantity of RME in biodiesel blends (B5, B20, B30) on the emission measurement of gaseous pollutants, such as: carbon monoxide (CO), hydrocarbons (HC), oxides of nitrogen (NOx), carbon dioxide (CO2) and particulate matter (PM) for light-duty-vehicle (LDV) during NEDC cycle on the chassis dynamometer as well as engine performance and reliability in engine dyno tests were analysed. All test results presented have been to standard diesel fuel. The measurement and analysis illustrate the capability of modern light-duty European diesel engines fueled with low and medium percentages of RME in biodiesel fuel with few problems.

The use of biofuels (biodiesel and gasoline-alcohol blends) in vehicle powertrains has grown in recent years in European Union, the United States, Japan, India, Brazil and many other countries due to limited fossil fuel sources and necessary reduction of anthropogenic CO2 emissions. European car manufacturers have approved up to 5 percent of biodiesel blend in diesel fuel (B5 biodiesel blend) which meets European fuel standards EN 14214 and EN 590. The goal for research is to achieve higher biodiesel content in diesel fuel B10 and B20, without resorting to larger diesel engines and fuel feed system modernization. This paper evaluates the possibility of using higher FAME content in biodiesel blends (mixture of diesel fuel and Fatty Acid Methyl Esters) in modern Euro 4 vehicle with direct-injection, common-rail and turbocharged light-duty diesel engine with standard engine ECU calibration and standard injection equipment (not tuned for biodiesel).

Research on the influence of oxygenated diesel fuels on the PM/NOx emission trade-off was carried out with use of 11 different synthetic oxygenated compounds, representing 3 chemical groups (glycol ethers, maleates, carbonates). Each of oxygenates were evaluated as a fuel additive at a concentration of 5% v/v in the same base diesel fuel. The tests were conducted on a passenger car equipped with a common rail turbocharged diesel engine over the European cycle NEDC and US FTP-75 cycle. All the tested oxygenates caused a reduction in PM emissions and most of them caused a certain increase in NOx emissions. The changes in emissions depended on the oxygenate type and cycle. In general, the favorable and unfavorable influence of oxygenated compounds was more intensive during the NEDC, which is a softer and less transient cycle than the FTP-75. The most favorable changes in the PM/NOx emission trade-off were obtained for maleates and carbonates.

This paper reviews the emissions from direct injection (DI) diesel engine in the initial period of controlled engine operation following start-up. The tests were undertaken in „cold start” mode (temperature of cooling water and lube oil equal to ambient temperature) and „warm start” mode* (after attaining a state of equilibrium). Both results were compared.

This paper reviews the exhaust emissions from direct injection diesel engines in the initial period following startup. The tests were undertake in “cold start” mode (temperature of cooling water and lube oil equal ambient temperature) and “warm start” modes (after getting equilibrium state). Both results were compared. Exhaust emissions in the period of run from cold start to warmed-up is very important to satisfy present day standards worldwide.

This paper reviews the exhaust emissions from direct injection (DI) diesel engines in the initial period following start-up. The tests were undertake in “cold start” mode (the temperature of the cooling water and lube oil being equal to the ambient temperature) and “warm start” modes (after achieving a state of equilibrium). The results from both states are compared. Exhaust emissions in the period from cold start is very important and must be improved in order to satisfy present day standards worldwide. A significant emission decrease during cold start can be achieved by incorporating selective fuel cut-off during the few seconds directly after beginning of engine crank. Compared to the acceptable gaseous pollutant concentrations, it was observed that an almost 50% reduction in hydrocarbon emission and a 30% reduction in carbon monoxide emissions were obtained (3 minutes of idle run).

The motor vehicle is one of the main sources of pollutant emissions, especially in urban areas. Environmentally friendly fuels are regarded as very effective means to decrease emissions. With regard to diesel engines, the reduction in nitrogen oxides and particulates are major problem areas. Although the fuel influence on NOx is comparatively low, the composition and parameters of diesel fuel have a big influence on particulate emissions and composition. Sulphur content is one of fuel proprieties, which has the most considerable influence on particulates. This paper describes results of the research on particulate emissions from diesel engines fuelled with research fuels of differing sulphur content. The sulphur content of the research fuels varied from 2000 ppm through 350 ppm (EURO III) and 50 ppm (EURO IV limit, which will be in force in the European Community from 1 January 2005) up to less than 5 ppm.

This paper reports testing conducted on multiple vehicle types over two European legislative driving cycles (the current NEDC and the incoming WLTC), using a mixture of legislative and non-legislative measurement devices to characterise the particulate emissions and examine the impact of the test cycle and certain vehicle characteristics (engine/fuel type, idle stop system, inertia) on particulate emissions. European legislative measurement techniques were successfully used to quantify particle mass (PM) and number (PN); an AVL Microsoot sensor was also used. Overall, the two driving cycles used in this study had a relatively limited impact on particulate emissions from the test vehicles, but certain differences were visible and in some cases statistically significant.

Cold starts are demanding events for spark-ignition (SI) internal combustion engines. When the temperatures of the engine oil, coolant and the engine block are close to the ambient temperature, start-up can be difficult to achieve without fuel enrichment, which results in significant excesses in exhaust emissions and fuel consumption. In general, the lower the ambient temperature, the more substantial these problems are. Many nations frequently experience sub-zero ambient temperatures, and the European Union (among others) has specified an emissions test at low ambient temperature (-7°C). Passenger cars typically experience one to two cold start events per day, and so both cold starts and the warm-up period that follows are significant in terms of exhaust emissions. This paper examines emissions at low ambient temperatures with a special focus on cold start; emissions are also compared to start-up at a higher ambient temperature (24°C).

A vital question for car manufacturers in countries where the temperature over night falls below freezing, is the significant increase of CO (carbon monoxide) and HC (hydrocarbon) emissions during the start and warm-up of spark ignition engines. ECE (Economic Commission for Europe) (UDC) (Urban Driving Cycle) cycles, divided into elementary phases, have been used to determine the level of harmful CO and HC emissions and fuel consumption in the cold start and warm up phase. Tests were undertaken on cars conditioned in temperatures ranging from +22°C to -15°C have shown significant increases in CO and HC as the temperature decreases.

For over a decade, the EU has required in-service conformity testing of heavy-duty road vehicles. This paper briefly discusses the practical aspects of the test requirements, how they have evolved and how they compare to other precedents, such as the heavy-duty engine dynamometer-based type approval testing procedure, as well as broadly equivalent EU requirements for light duty vehicles. Emissions requirements for heavy-duty vehicles are work-specific, but based on standard test results a range of other parameters can be calculated to yield distance-specific, tonnage-distance specific, CO2-specific and (gravimetric) fuel-specific results. At present, CO2 and fuel consumption are not subject to any limits per se during on-road testing (and this is the case for both heavy and light duty vehicles); nevertheless, the aforementioned parameters must be measured and such results can be of interest for a variety of reasons.

The European driving cycle, deleting the first 40 seconds of idle after the start up phase, and the US FTP 75 cycle are compared in this paper. The paper presents an analysis of emission tests for CO, HC and NOx measured during tests performed on a chassis dynamometer under laboratory conditions. The tests are reviewed and the results discussed. The objective of the study was to determine the influence of the test cycle on the measured emission of CO, HC and NOx, and the changes of fuel consumption at the initial phase of engine operation. Differences in catalyst warm up rates when running NEDC, ECE + EUDC and FTP 75 cycles are demonstrated. Methods of reduction in these harmful emissions and the results of tests with new technologies targeted at the reduction of CO, HC and NOx under cold start are also discussed.