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In the present work, the partial oxidation of diesel (US07), rapeseed methyl ester (RME) and low temperature Fischer - Tropsch synthetic diesel (SD), almost 100% paraffinic, was investigated for the purpose of hydrogen and intermediate hydrocarbon species production over a prototype reforming catalyst, for the potential use in hydrocarbon selective catalytic reduction (HC-SCR) of nitrogen oxide (NOx) emissions from diesel engines. The presence of small amounts of hydrogen can substantially improve the effectiveness of hydrocarbons in the selective reduction of NOx over lean NOx catalysts, particularly at low temperatures (150-350°C). In this study, the partial oxidation reactor was operating at the same input power (kW), based on the calorific values of the fed fuel. Hydrogen production was as high as 19%, from the partial oxidation of SD fuel, and dropped to 17% and 14% for RME and US07 diesel, respectively.

Addition of nitroalkanes to gasoline is shown to reduce the octane quality. The reduction in the Motor Octane Number (MON) is greater than the reduction in the Research Octane Number (RON). In other words addition of nitroalkanes causes an increase in octane sensitivity. The temperature of the compressed air/fuel mixture in the MON test is higher then in the RON test. Through chemical kinetic modelling, we are able to show how the temperature dependence of the reactions responsible for break-up of the nitroalkane molecule can lead to an increase in octane sensitivity. Results are presented from an Homogenous Charge Compression Ignition (HCCI) engine with a homogeneous charge in which the air intake temperature was varied. When the engine was operated on gasoline-like fuels containing nitroalkanes, it was observed that the combustion phasing was much more sensitive to the air intake temperature. This suggests a possible means of controlling combustion phasing for HCCI.

This article presents a detailed kinetic mechanism for the combustion of surrogate gasoline fuels (mixtures of primary reference fuels and toluene) that has been developed by modification of a previous mechanism (Andrae et al., 2007). The modifications introduced were: (i) revision of the sub-mechanisms associated with H2, CO and CH4 oxidation and (ii) retuning of rate coefficients of reactions involved in the i-octane oxidation sub-mechanism. The first set of modifications made use of new kinetic parameters evaluated by the CODATA project (Baulch et al. 2006), whereas the second was prompted by a sensitivity analysis of the mechanism obtained after implementation of (i). The resulting mechanism, which describes the low, intermediate and high temperature combustion regimes, is used to study pre-ignition of surrogate gasoline fuels. Comparison of the simulation data with experimental measurements over a wide range of conditions reveals a good agreement.

Lubricant samples were aged on a SI bench engine that was run using ten different gasoline fuels. For each gasoline tested, the oxidative stability of the lubricant and the extent of engine wear was assessed in terms of a number of different parameters. Surprisingly, it was found that fuels containing higher levels of olefin (whether C8 olefin, or a C5/C6 olefin blend, or a catalytically cracked refinery stream) performed directionally better than a reference gasoline with low levels of aromatics and olefins. Fuels with a higher final boiling point and higher aromatic content, appeared to be associated with enhanced levels of sludge formation than the reference gasoline, but did not give rise to enhanced engine wear.