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Diesel exhaust systems equipped with selective catalytic reduction (SCR) catalysts based on urea were subjected to an aging process where the exhaust gas temperature was below 300°C. Solid deposits related to urea injection were found on the wall of the exhaust pipe down stream of the urea injector and on a urea mixer in front of the SCR catalyst. In laboratory tests, an aqueous solution of urea (1.5wt%) was dripped onto an SCR catalyst core in a simulated lean gas mixture at a rate corresponding to a 1:1 NH3-to-NOx ratio (NOx = 350ppm) and a space velocity (SV) of 15,000 h-1 at various temperatures. At 300°C and below, urea-related deposits appeared on the SCR catalyst surface and totally plugged the SCR catalyst monolith within 250 hours. When the aging temperature was 350°C or above, no deposits were observed on the SCR catalyst core.

Painting is the most difficult, the most costly, and the most polluting step in manufacturing vehicles. When low weathering performance paints are used, the results are dissatisfied customers, and huge warranty costs. It would obviously be wise to fully characterize the weathering performance of new coatings systems before they are used. Unfortunately this is not always practical. Coating formulations are changing rapidly in the States to comply with solvent emission regulations, the introduction of plastic substrates, and customer tastes. There is rarely enough time to wait ten years for outdoors exposure tests to reveal the "true" weathering performance of coatings before marketing vehicles. As a result, accelerated tests are often used to guide decisions. However, the results of such tests can be misleading because the harsh exposure conditions used can distort the chemistry of degradation.