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This study reports the performance of three different automotive magnesium substrate materials (AM60B diecastings, AZ31-H24 sheet, and AM30 extrusions), each bonded to a common aluminum reference material with two different toughened adhesives. The magnesium substrates were pretreated with six different commercial pretreatments both with and without a final fused-powder polymeric topcoat. These samples were then evaluated by comparing initial lap-shear strength to the lap-shear strength after cyclic-corrosion testing. Additionally, use of a scribe through the polymer primer permitted assessment of: 1) distance of corrosion undercutting from the scribe (filiform), and 2) percent corrosion over the area of the coupon. The results showed that the performance of each magnesium pretreatment varied on cast AM60B, sheet AZ31-H24, and extruded AM30 substrates.

General corrosion protection of sheet materials such as steel used in automobile construction has reached a high level of performance, due primarily to the incorporation of mill-applied treatments such as electrogalvanizing, galvannealing and other coil-coating processes developed over the last half century. While such treatments have greatly extended the corrosion resistance of steel and its various body constructs, attention is now focused on aspects of the manufacturing process wherein these intended protections are compromised by such features as weldments, joins, cut edges and extreme metal deformations such as hems. A novel metal deposition process, based on high-velocity impact fusion of solid metal particles, has been used to extend the corrosion resistance of base steel and pre-galvanized sheet, by selectively placing highly controlled depositions of zinc and other sacrificial materials in close proximity to critical manufacturing details.