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Controlled auto ignition (CAI) is a form of combustion which uses an auto-ignited homogeneous air/fuel mixture but is controlled (or moderated) by regulating the quantity of internal exhaust gas residuals. In this paper, using a fully variable valve train and a newly developed exhaust valve control strategy, we substituted EGR with hot nitrogen or hot air. We found that the internal exhaust gas residuals have both thermal and chemical effects on CAI combustion. To investigate the thermal effect, nitrogen was used as it is a chemically inert gas. Although its temperature was raised to that of the internal exhaust gas residuals during testing, CAI combustion could not be promoted without assistance from a spark in a form of hybrid CAI, thus indicating that exhaust gas residuals have a chemical effect as well.