Search Results

Extensive research has been performed for on-board hydrogen generation, such as pyrolysis of metal hydrides (e.g., LiH, MgH₂), hydrogen storages in adsorption materials (e.g., carbon nanotubes and graphites), compressed hydrogen tanks and the hydrolysis of chemical hydrides. Among these methods, the hydrolysis of NaBH₄ has attracted great attention due to the high stability of its alkaline solution and the relatively high energy density, with further advantages such as moderate temperature range (from -5°C to 100°C) requirement, non-flammable, no side reactions or other volatile products, high purity H₂ output. The H₂ energy density contained by the system is fully depend on the solubility of the complicated solution contains reactant, product and the solution stabilizer. In this work, an approach based on thermodynamic equilibrium was proposed to model the relationship between the solubility of an electrolyte and temperature, and the effect of another component on its solubility.