Technical Paper
A Comparison of Methanol and Dissociated Methanol Illustrating Effects of Fuel Properties on Engine Efficiency—Experiments and Thermodynamic Analyses
1985-02-01
850217
Methanol, a popular alternative fuel candidate, can theoretically be dissociated on-board a vehicle into a 2/1 molar mixture of hydrogen (H2) and carbon monoxide (CO) having a 14 percent greater heating value than that of methanol vapor. In this study, engine efficiency and fuel consumption with methanol vapor and dissociated methanol (simulated by a 2/1 mixture of Ha and CO) were compared in a single-cylinder engine at equivalence ratios (Φ’s) ranging from 0.5 to 0.9 and compression ratios (CR’s) from 11 to 14. Whan compared at the same Φ and CR, the reduction in fuel consumption for dissociated methanol compared to methanol (3-7 percent) was smaller than would be expected based on heating value alone. Indicated thermal efficiency with dissociated methanol was only 0.89-0.55 times that with methanol. Thermodynamic analyses were conducted to isolate the factors responsible for lower efficiency with dissociated methanol.
