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Our research objective is to clarify the effect of the utilization of diesel fuels made from unconventional petroleum sources (GTL, Tar Sand, etc.) on the latest vehicle‛s emission and performance. The target properties studied are mainly cetane number and cyclic compounds. Two diesel vehicles and one engine were used in this study. Varieties of transient driving modes were selected for better understanding under real world driving in the emission test. Startability and operability are examined in the vehicle performance test. It was revealed that the tail-pipe emission from a J-2003 reg-compliant vehicle and the engine-out emission from a J-2005 reg-compliant engine used in this study were changed by cetane number and cyclic compound. For J-2003 reg-compliant vehicle, the decrease in cetane number led to the increase in emissions of THC, CO and NOx, while the increase in cyclic compounds led to increase in emissions of PM, THC, CO and NOx.