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This is a first of a series of papers describing how the replacement of some of the inlet air with EGR modifies the diesel combustion process and thereby affects the exhaust emissions. This paper deals with only the reduction of oxygen in the inlet charge to the engine (dilution effect). The oxygen in the inlet charge to a direct injection diesel engine was progressively replaced by inert gases, whilst the engine speed, fuelling rate, injection timing, total mass and the specific heat capacity of the inlet charge were kept constant. The use of inert gases for oxygen replacement, rather than carbon dioxide (CO2) or water vapour normally found in EGR, ensured that the effects on combustion of dissociation of these species were excluded. In addition, the effects of oxygen replacement on ignition delay were isolated and quantified.