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Ceria has become an increasingly important component in automotive exhaust catalysts over the past decade. Recently, with the proposal that measurements of oxygen storage be used for the on-board evaluation of catalyst performance for both low emission vehicles (LEV) and non-LEV vehicles, understanding the role of ceria and its deterioration with catalyst aging has become even more important. It is well established that ceria in an alumina support promotes oxygen storage/release by automotive catalysts under cycled air/fuel conditions, which in turn promotes the catalyst's conversion performance under those conditions. Another benefit of ceria is its enhancement of the catalytic activity for other reactions, such as the water-gas shift reaction under rich conditions. In addition, ceria may help catalyst durability by promoting precious metal dispersion and playing some role as a stabilizer of the support.

Three vehicle and dynamometer-aged converters were evaluated for performance using the warmed-up portion (termed the “hot-18” cycles) of the Federal Test Procedure (FTP) and during a steady-state cruise using low and high sulfur content fuel. During the steady-state tests the catalyst performance was also monitored using two oxygen sensors designed to satisfy Phase II On-Board Diagnostics (OBD-II) requirements for vehicles sold in California in MY 1994 and thereafter. The performance of two of the converters decreased significantly upon switching to the high sulfur content fuel, and one of the converters which was diagnosed as passing with low sulfur fuel was diagnosed as failing with high sulfur fuel.