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Hydrogen produced from regenerative sources has the potential to be a sustainable substitute for fossil fuels. A hydrogen internal combustion engine has good combustion characteristics, such as higher flame propagation velocity, shorter quenching distance, and higher thermal conductivity compared with hydrocarbon fuel. However, storing hydrogen is problematic since the energy density is low. Hydrogen can be chemically stored as a hydrocarbon fuel. In particular, an organic hydride can easily generate hydrogen through use of a catalyst. Additionally, it has an advantage in hydrogen transportation due to its liquid form at room temperature and pressure. We examined the application of an organic hydride in a spark ignition (SI) engine. We used methylcyclohexane (MCH) as an organic hydride from which hydrogen and toluene (TOL) can be reformed. First, the theoretical thermal efficiency was examined when hydrogen and TOL were supplied to an SI engine.

Impact of oil-derived ash on the pressure drop of continuous regeneration-type diesel particulate filter (CR-DPF) was investigated through 600hrs running test at maximum power point on a 6.9L diesel engine, which meets the Japanese long-term emission regulations enacted in 1998, using approximately 50ppm sulfur content fuel. Sulfated ash content of test oils were varied as 0.96, 1.31, and 1.70 mass%, respectively. During the running test, the exhaust pressure drop through CR-DPF was measured. And after the test, the ventilation resistance through CR-DPF was also evaluated before and after the baking process, which was applied to eliminate the effect of soot accumulated in CR-DPF. The results revealed that the less sulfated ash in oil gave rise to lower pressure drop across CR-DPF. According to microscope examination of the baked DPF, ash was mainly accumulated on the wall surface of CR-DPF, and that seemed to be related to the magnitude of pressure drop caused by ash.

Bio-ethanol can be produced from several type of biomass, and the CO2 emission of bio-ethanol is low compared with gasoline. Bio-ethanol is a high octane fuel, therefore, it has characteristics that allow it to burn at a high compression ratio condition. However, bio-ethanol is usually refined to be high purity ethanol (>99.5%). It requires much energy to refine; thus large-scale refinery plants are needed, increasing the cost of refining bio-ethanol. High purity ethanol (>99.5%) can be refined after fermentation and a distillation. If hydrous ethanol can be used as a fuel for engines, the distillation process can be simplified. As a result, the costs of refinement can be reduced. An innovated engine can be developed by using hydrous ethanol as the fuel because three highly efficient methods can be combined. First, exhaust heat can be recovered by the steam reforming of hydrous ethanol. Second, the reformed gas, which contains hydrogen, can be combusted under dilute conditions.

The internal combustion engines waste large amounts of heat energy, which account for 60% of the fuel energy. If this heat energy could be converted to the output power of engines, their thermal efficiency could be improved. The thermal efficiency of the Otto cycle increases as the compression ratio and the ratio of specific heat increase. If high octane number fuel is used in engines, their thermal efficiency could be improved. Moreover, thermal efficiency could be improved further if fuel could be combusted in dilute condition. Therefore, exhaust heat recovery, high compression combustion, and lean combustion are important methods of improving the thermal efficiency of SI engines. These three methods could be combined by using hydrous ethanol as fuel. Exhaust heat can be recovered by the steam reforming of hydrous ethanol. The reformed gas including hydrogen can be combusted in dilute condition. In addition, it is cooled by directly injecting hydrous ethanol into the engine.