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Differences in thermo-physical parameters of fuels have high impact on the ignition, combustion and emission. Pure rapeseed FAME and diesel fuel with a cetane number of 60 have been compared to reference fuel. In an optical accessible vessel the fuels have been injected in order to investigate the spray, the ignition and soot formation. The high cetane number fuel showed similar behavior in spray phase to the reference fuel but the FAME fuel is more present at all operating points due to low volatile fuel components. The ignition and combustion process was investigated via chemical luminescence (CL) and laser induced incandescence (LII). In engine investigations a reduced ignition delay is detected in case of high cetane-number. The more sensitive optical techniques show differences in the combustion process. The ignition behavior of the reference fuel and the increased cetane number fuel were similar until the cetane increaser of the high cetane fuel came into effect.

Worldwide diesel fuels differ in their composition and therefore in thermo-physical properties. Some of these properties are known to have little effect on the combustion process. Others, like the cetane number, have dramatic influence on the combustion formation and thus on the heat release rate and more important the formation of soot and NOx. In an experiment series various commercially available fuel types, like EN 590 [1], ASTM D975 [2] and JIS K 2204 [3], have been compared to alternative diesel fuels such as FAME, GtL and premium diesel fuel with increased cetane number. A specially designed research injector was used in order to provide full optical access to one single fuel jet injected and combusted in a constant volume vessel. First, the liquid fuel phase propagation has been investigated by means of Mie-scattering and the liquid penetration depth and the spray cone angle have been evaluated.