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Various fluorescence tracers were assessed for their applicability for simultaneously measuring fuel distributions of different volatility classes. Tracers were chosen to show significantly different boiling behaviour representing three volatility classes of non-fluorescing multi-component fuels. Fluorescence properties of the markers were investigated using a heated static high-pressure cell with respect to emission behaviour, temperature and pressure dependence and quenching influences. A combination of ketonic and aromatic tracers appeared to be ideal for simultaneous imaging purposes since fluorescence is emitted in separate spectral regions with little overlap. Simultaneous measurements of the fuel distribution of two volatility classes were performed in a port fuel injected engine showing significant differences in the fuel distributions of low and mid boiling fractions in early stages of compression.

Optical imaging diagnostics of combustion are most often performed in the visible spectral band, in part because camera technology is most mature in this region, but operating in the infrared (IR) provides a number of benefits. These benefits include access to emission lines of relevant chemical species (e.g. water, carbon dioxide, and carbon monoxide) and obviation of image intensifiers (avoiding reduced spatial resolution and increased cost). High-speed IR in-cylinder imaging and image processing were used to investigate the relationships between infrared images, quantitative image-derived metrics (e.g. location of the flame centroid), and measurements made with in-cylinder pressure transducers (e.g. coefficient of variation of mean effective pressure). A 9.7-liter, inline-six, natural-gas-fueled engine was modified to enable exhaust-gas recirculation (EGR) and provide borescopic optical access to one cylinder for two high-speed infrared cameras.

The transient cone angle of a pressure swirl spray from an injector for gasoline direct injection engines was measured from 2D Mie scattering images. Iso-octane was used as the fluid that was delivered at room temperature for two different static pressures, 5MPa and 8.5MPa. The iso-octane was injected into a chamber at room temperature and ambient pressure. After a rapid initial increase, the cone angle oscillates before stabilizing to a steady-state value very close to the nominal cone angle. The period of the oscillation was found to correlate well with oscillations measured in the fuel line pressure.

The transient cone angle of pressure swirl sprays from injectors intended for use in gasoline direct injection engines was measured from 2D Mie scattering images. A variety of injectors with varying nominal cone angle and flow rate were investigated. The general cone angle behavior was found to correlate well qualitatively with the measured fuel line pressure and was affected by the different injector specifications. Experimentally measured modulations in cone angle and injection pressure were forced on a comprehensive spray simulation to understand the sensitivity of pulsating injector boundary conditions on general spray structure. Ignoring the nozzle fluctuations led to a computed spray shape that inadequately replicated the experimental images; hence, demonstrating the importance of quantifying the injector boundary conditions when characterizing a spray using high-fidelity simulation tools.

For applications of planar laser induced fluorescence (PLIF) to measure the fuel or equivalence ratio distributions in internal combustion (IC) engines it is typically assumed that the addition of a fluorescence tracer to a base fuel does not alter the combustion performance. We have investigated the impact on combustion performance through the addition of various amounts of 3-pentanone or toluene to iso-octane fuel. Correlations between equivalence ratio for a range of fuel/tracer mixtures and engine parameters, like peak pressure, location of peak pressure, indicated mean effective pressure (IMEP), and peak burn rate are discussed for data obtained in a spark-ignition direct-injection (SIDI) gasoline engine operated with near homogeneous charge. For typical tracer concentrations the impact on combustion performance is mostly negligible.

Quantitative planar laser-induced fluorescence measurements of fuel/air mixing in engines are usually based on the use of fluorescence tracers. The strength of the signals often depends on temperature, pressure and mixture composition. This complicates a quantitative analysis. The use of a small-bore optical engine for fundamental studies of absorption and fluorescence properties of fluorescence tracers is described. The temperature, pressure and composition dependence of the spectra of toluene, acetone, 3-pentanone, and biacetyl are examined under motored conditions to extend the experimental data base for the development of comprehensive models that predict the strength of fluorescence signals for a given condition.