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The effects of cetane number and the cetane enhancing additives on diesel exhaust emissions were investigated on a single cylinder DI research engine. The engine used in this study incorporates the features of contemporary medium-to-heavy duty diesel engines and is tuned to US EPA 1994 emission standards. The engine experiments were run using the AVL 8-mode steady-state simulation of the U.S. EPA heavy-duty transient test procedure. The experimental fuels included diesel fuels obtained from different sources with various natural cetane ratings as well as a number of fuels blended by adding two cetane improvers into three base fuels. The two cetane improvers we used were a nitrate-type additive and a peroxide-type additive. Increasing the cetane number resulted in a general decrease in NOx emissions. Similar reductions in NOx emissions were observed with increasing cetane number for all the base fuels irrespective of the cetane improver used in the fuel.