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In the early years of antifreeze/coolants (1920s & 30s) glycerin saw some usage, but because of higher cost and weaker freeze point depression, it was not competitive with ethylene glycol. Glycerin is a by-product of the manufacture of biodiesel (fatty acid methyl esters) made by reacting natural vegetable or animal fats with methanol. Biodiesel fuel is becoming increasingly important and is expected to gain a large market share in the next several years. Regular diesel fuels blended with 2%, 5%, and 20% biodiesel are now commercially available. The large amount of glycerin generated from high volume usage of biodiesel fuel has resulted in this chemical becoming cost competitive with the glycols currently used in engine coolants. For this reason, and lower toxicity comparable to that of propylene glycol, glycerin deserves to be reconsidered as a base for antifreeze/coolant.

Conventional diesel fuel (1) has been on the market for decades and used successfully to run diesel engines of all sizes in many applications.* In order to reduce emissions and to foster energy source diversity, new fuels such as alternative and renewable, as well as new formulations, have entered the market. These include biodiesel, gas-to-liquid, and alternative formulations by states such as California. Performance variations in fuel economy, emissions, and compatibility for these fuels have been evaluated and debated. In some cases, contradictory views have surfaced. “Renewable” and “clean” designations have been interchanged. Adding to the confusion, results from one fuel in one type of engine, such as an older heavy-duty engine, is at times compared to that of another type, such as a modern light-duty engine.