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Hydrogen engines are required to provide high thermal efficiency and low nitrogen oxide (NOX) emissions. There are many possible combinations of injection timing, ignition timing, lambda and EGR rate that can be used in a direct-injection system for achieving such performance. In this study, NOX emissions of natural aspirated 4 cylinders engine with management strategies involving the injection timing, ignition timing, lambda and the EGR rate were evaluated under a Japanese JE05 emissions test cycle. Finally, the paper projects the potential of direct injection hydrogen engine for obtaining high output power and attaining low NOX emissions of 0.7 g/kWh under the emission test cycle.

A natural gas direct injection test engine equipped with a newly developed natural gas injector was built. High total hydrocarbon (THC) emission at part-load and high NOx emission at high-load remain as problems for direct injection natural gas engines. THC reduction and combustion improvement by throttling and NOx reduction by EGR were investigated. The following results were obtained: (1) the combustion at light and medium load conditions is improved by throttling. It is possible to improve the thermal efficiency at light-load in spite of the pumping loss by throttling. THC emissions are greatly decreased in this condition; (2) a large NOx reduction can be obtained without combustion deterioration by appropriate EGR at high-load conditions; and (3) it is possible to decrease both THC and NOx emissions by both throttling and EGR at part-load conditions.

In recent years, attention has focused on smokeless, sulfur-free dimethyl ethyl (DME) as a clean fuel for heavy-duty diesel vehicles [1]. In this development, the DME engine applied for 20-ton GVW truck was developed under the auspices of the Ministry of Land, Infrastructure and Transport of Japan, the first known instance worldwide. With careful design of the fuel system considering DME's unique fuel characteristics and suitable combustion improvement, higher torque was obtained with DME, compared to diesel fueling. and also use of the proper EGR and catalyst, exhaust emissions levels were generally less than one-fourth of new long-term regulation value promulgated in 2005 Japan.

Exhaust gas recirculation (EGR) was applied in a spark-assisted, direct-injection (Dl) neat methanol engine for light duty vehicles. An experimental study has been carried out to analyse for major factors of EGR that influence in the reduction of NOx mass emission and improvement in brake thermal efficiency. EGR on the Dl methanol engine alters intake charge, especially increasing the concentrations of H2O and unburned methanol with rising intake charge temperature. The results of qualitative analyses show that this phenomenon suppresses rapid heat generation at the initial combustion stage, therefore lowering the combustion temperature in the cylinders and leading to a reduction in NOx production.

NOx selective reducing catalysts are expected to be used for lean-burn gasoline engines and diesel engines as an effective NOx reduction measure. We are interested in the combination of methanol, as a reducing agent, and alumina catalyst, and have considered the NOx reduction method using effectively much unburned methanol. In this report, in order to investigate the effect of NOx reduction by the alumina catalyst, the experiment was carried out by feeding the actual exhaust gas from the methanol engine into the alumina catalyst. As a result, it was confirmed that, without addition of any other reducing agents into the exhaust gas, the alumina catalyst has activity to reduce NOx.

It is well known that during engine cold-start, methanol fueled vehicles have a tendency to emit significant amount of unburnt methanol and formaldehyde, which is an oxidant of methanol The emission behavior and reduction methods of these components are studied in this paper The reduction rate of these unburnt components exceeds 99% when the temperature of a catalyst is enough high However during engine cold-start the oxidative reaction can not begin, and it takes several minutes to warm up the catalyst After the temperature of the catalyst reaches to the light-off temperature it rises steeply and high reduction rates of these components are obtained at the same time Therefore, the catalyst temperature must be raised quickly and effectively in order to realize the proper oxidative reduction of unburnt methanol and formaldehyde emissions during engine cold-start Consequently the effectiveness of installing pre-catalysts was examined in this study Some pre-catalysts (200cm3/piece) were placed after the exhaust manifold Results showed that within 10 minutes of initiating the idling experiment after engine cold-start the pre-catalysts were very effective and decreased emissions of the unburnt components by two thirds Moreover pre-catalysts which were electrically pre-heated with an external heater could more drastically decrease the amount of these components under the same experimental conditions However for such electrical heating to be practical it is necessary to reduce the level of heating energy to as low an amount as possible Therefore two power-saving methods were tried One method consisted of installing a glow plug in the upper stream of the pre-catalyst This method was based on an idea that unburnt components coming in contact with the glow plug are activated and easily oxidized and that they then release thermal energy for quick heating The results showed that this method was effective for reduction (more than 40%) of unburnt methanol but was ineffective for reducing formaldehyde since spot heating caused a balancing of formaldehyde formation/decomposition Therefore another method was examined A small-sized electric heated pre-catalyst(50cm3)was installed in order to heat a full section of the exhaust stream of the catalyst The results showed that this method had a great effect in reducing these harmful substances Moreover, it was demonstrated that this method consumes little energy and is more practical as a means of heating

In this study, we investigated the combustion technology for the direct injection (DI) methanol engine for a heavy-duty vehicle that makes use of the fuel characteristics of methanol and achieves smokeless burning with high efficiency and low NOx emissions under the heavy load condition. A 3.3-liter 4-cylinder spark-assisted DI methanol engine was tested to investigate the combustion and NOx emission characteristics under the full load condition with supercharging and/or EGR. We believe that supercharging suppressed the stratified charge combustion, but accelerated the premixed combustion to increase the indicated mean effective pressure. Moreover, supercharging was helpful in carrying out EGR under the full load condition without deteriorating the thermal efficiency. Furthermore, heavy EGR during supercharging reduced the NOx emissions dramatically while maintaining the high thermal efficiency and controlling the unburned hydrocarbons emissions.

In recent years, the dimethyl ether (DME) fuel has been attracting attention as an alternative engine in terms of diesel utilization. This is (a) because its cetane number is close to that of diesel fuel, (b) an innovative chemical process has been developed to produce DME efficiently from natural gas and coal, and (c) DME as a fuel has fewer environment-polluting characteristics than diesel fuel. Inasmuch as DME fuel have lower molecular weights, a molecular C-O bond, and are much more volatile or evaporative than diesel fuel, it is possible to control particulate matters much more easily when DME is used instead of diesel fuel. As for NOx, however, even when using DME, there still remain problems under stringent exhaust gas regulations. Developed and optimized accordingly has been the NOx storage-reduction (NSR) system, using the DME engine with a common-rail injection system. The NSR system is coated with an NOx storage catalyst principally comprised of Pt and Rh.

The effects of methanol and EGR on HCCI combustion of dimethyl ether have been tested separately in a diesel engine. The engine was equipped with a common rail injection system which allowed for random injection of DME. The engine could therefore be operated either as a normal DI CI engine or, by advancing the injection timing 360 CAD, as an HCCI engine. The compression ratio of the engine was reduced to 14.5 by enlarging the piston bowls. The engine was operated in HCCI mode with DME at an equivalence ratio of 0.25. To retard the combustion timing, methanol was port fuel injected and the optimum quantity required was determined. The added methanol increased the BMEP by increasing the total heat release and retarding the combustion to after TDC. Engine knock was reduced with increasing quantities of methanol. The highest BMEP was achieved when the equivalence ratio of methanol was around 0.12 at 1000 RPM, and around 0.76 at 1800 RPM. EGR was also used to retarding the timing.