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Several types of oxidation catalyst material are tested in repeated particulate emission measurements over the US HDD transient test procedure. Particulates are effectively reduced in the initial stage of the measurements. However, particulates tend to increase when repeating the measurements. This is believed to be caused by sulfate adsorption on the catalyst surfaces. Hence, oxidation catalysts are tested after stabilizing surface adsorption. Test results show that an oxidation catalyst which forms more sulfates is not effective in reducing particulates because the sulfate increase offsets the SOF reduction effect. An effective catalyst for particulate reduction is developed by suppressing sulfate formation.

The effects of fuel properties on diesel engine exhaust emission characteristics are investigated using eleven kinds of fuel with varying levels of sulfur and aromatic contents. Exhaust emissions from three engines are measured over the new Japanese 13-mode cycle as well as the U.S. transient test procedure. Engine test results show that reducing the fuel sulfur content decreases particulate levels. This effect is more pronounced for engines that emit more SOF. Enriching the aromatic content with dicyclic and other polycyclic compounds increases particulate, NOx, CO, and THC emissions. This particulate increase is due to the increase of SOF. Accordingly, low sulfur fuel should be produced without increasing the aromatic content, otherwise the SOF increase will offset the particulate reduction effect of the low sulfur fuel.