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One dimensional Spontaneous Raman Scattering measurements (RS) have been performed in a spray (standard gasoline, one-component and multi-component model fuels) which was operated in a high-temperature, high-pressure chamber, so that realistic engine conditions have been simulated. The present work investigates under what conditions 1D-RS can be employed for fuel/air-ratio measurements in realistic DI gasoline sprays. The distance from the spray axis has been determined, til that, coming from the outside, quantitative Raman measurement are possible. The equivalence ratio has been quantified for the one component fuel close to the spray. It turns out that the measurement error depends strongly on the type of fuel. These problems are caused by the PAH (polycyclic aromatic hydrocarbon) content of the fuel, which leads to interfering laser-induced fluorescence signals.

The paper describes detailed studies about the spray formation of a direct-injection high-pressure gasoline injector and the interaction of the droplets with the surrounding compressed air in pressure chamber experiments and inside an optically accessible research engine. Different optical techniques, like stroboscopic video technique, high-speed filming with flood-light illumination or with light-sheet illumination by a copper vapour laser, particle image velocimetry of the droplets, laser-induced fluorescence of the liquid phase, and spontaneous Raman spectroscopy for the measurement of the fuel/air ratio are used. From the recorded images spray characteristics such as spray penetration and spray cone angle are evaluated for different settings of the chamber pressure and temperature and for different rail pressures. The results show that all techniques are suitable to derive the quantities mentioned above.