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Homogeneous Charge Compression Ignition (HCCI) combustion has attracted much interest as a combustion system that can achieve both low emissions and high efficiency. But the operating region of HCCI combustion is narrow, and it is difficult to control the auto-ignition timing. This study focused on the use of a two-component fuel blend and supercharging. The blended fuel consisted of dimethyl ether (DME), which has attracted interest as alternative fuel for compression-ignition engines, and methane, the main component of natural gas. A spectroscopic technique was used to measure the light emission of the combustion flame in the combustion chamber in order to ascertain the combustion characteristics. HCCI combustion characteristics were analyzed in detail in the present study by measuring this light emission spectrum.