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Because niobium-clad 304L stainless steel sheets are considered for use as bipolar plates in polymer electrolyte membrane (PEM) fuel cells, their mechanical behavior and failure mechanism are important to be examined. As-rolled and annealed specimens were tested in tension, bending and flattening. The effects of annealing temperature and time on the mechanical behavior and failure mechanism were investigated. Micrographic analyses of bent and flattened specimens showed that the as-rolled specimens have limited ductility and that the annealed specimens can develop an intermetallic layer of thickness of a few microns. The annealed specimens failed due to the breakage of intermetallic layer causing localized necking and the subsequent failure of Nb layer. The springback angles of the as-rolled and annealed specimens were also obtained from guided-bend tests.

A laboratory study was performed to optimize a zoned configuration of an iron (Fe) SCR catalyst and a copper (Cu) SCR catalyst in order to provide high NOx conversion at lean A/F ratios over a broad range of temperature for diesel and lean-burn gasoline applications. With an optimized space velocity of 8,300 hr-1, a 67% (by volume) Fe section followed by a 33% Cu section provided at least 80% NOx conversion from approximately 230°C to 640°C when evaluated with 500 ppm NO and NH3. To improve the lean lightoff performance of the SCR catalyst system during a cold start, a Cu SCR catalyst that was 1/4 as long as the rear Cu SCR catalyst was placed in front of the Fe SCR catalyst. When evaluated with an excess of NH3 (NH3/NO ratio of 2.2), the Cu+Fe+Cu SCR system had significantly improved lightoff performance relative to the Fe+Cu SCR system, although the front Cu SCR catalyst did decrease the NOx conversion at temperatures above 475°C by oxidizing some of the NH3 to N2 or NO.

A laboratory study was performed to assess the effects of SO2 poisoning on the NOx conversion of iron (Fe) and copper (Cu) SCR catalysts. Thermally aged samples of the catalysts were poisoned with SO2 under lean conditions. At various times during the poisonings, the samples were evaluated for NOx conversion with NO and NH3 using lean temperature ramps. The low temperature NOx conversions of both catalysts decreased by 10 to 20% after 1 to 4 hours of poisoning but were stable with continued exposure to the SO2. The poisoned Cu SCR catalyst could be desulfated repeatedly with 5 minutes of lean operation at 600°C. Initially, the poisoned Fe SCR catalyst required 5 minutes of lean operation at 750°C to recover its maximum NOx conversion.

Many engineers have been working to reduce brake noise in many ways for a long time. So far, a progress has been made in preventing and predicting brake noise. Nevertheless, there are some discrepancies of brake noise generation propensity between testing for the prototype and the production. As known in general, the reason for this unpredicted brake noise occurrence in production is partly due to the variation of the resonant frequency, material and the other unpredictable or unmanageable variations of the components in a brake system. In this paper, effects of chemical components and casting process of gray iron brake disc on its resonant frequency variation have been studied. Especially this paper is focused on the variation in material aspects and manufacturing parameters during disc casting in usual production condition. And their effects are investigated by the variation of out-of-plane modal resonant frequency.

During braking, third-body flows and layers govern friction mechanisms, which are fully responsible of the friction coefficient and wear. In the context of development of brake friction pairs, the involved tribological circuit has to be well understood and mastered. This paper concerns a sintered metal matrix composite used for TGV very high speed train. A series of low-energy stop brakings allows a detailed study of the third-body formation at the pad-disc contact. The pin surface is observed after each test. The evolution of the rubbing-area expansion all along the series is explained, and the friction behaviour, typical of the studied friction material, is related to the formation of a well-established third body at the pad-disc interface.

Compliance with tighter emission regulations has increased the proportion of parasitic weight in commercial vehicles. In turn, the amount of payload must be reduced to comply with transportation weight requirements. A re-design of commercial vehicle components is necessary to decrease the vehicle weight and improve payload capacity. Side rails have traditionally been manufactured from high strength steels, but significant weight reductions can be achieved by substituting steel side rails with 6013 high strength aluminum alloy side rails. Material and stress analyses are presented in this paper in order to understand the effect of manufacturing process on the material's mechanical behavior. Metallographic and tensile test experiments for the 6013-T4 alloy were performed in preparation for residual stress measurements of a punching operation. Punched holes are critical to the function of the side rail and can lead to high stress levels and cracking.

In this paper, the microstructure-based finite element modeling method is used in investigating the loading path dependence of formability of transformation induced plasticity (TRIP) steels. For this purpose, the effects of different loading path on the forming limit diagrams (FLD) of TRIP steels are qualitatively examined using the representative volume element (RVE) of a commercial TRIP800 steel. First, the modeling method was introduced, where a combined isotropic/kinematic hardening rule is adopted for the constituent phases in order to correctly describe the cyclic deformation behaviors of TRIP steels during the forming process with combined loading paths which may include the unloading between the two consecutive loadings. Material parameters for the constituent phases remained the same as those in the authors' previous study [ 1 ] except for some adjustments for the martensite phase due to the introduction of the new combined hardening rule.

Predicting AHSS cracking during crash events and forming processes is an enabling technology for AHSS application. Several fracture criteria including MatFEM and Modified Mohr-Coulomb Criterion were developed recently. However, none of them are designed to cover more fracture modes such as bending fracture and tearing fracture with initial damage. A mixed-mode fracture criterion (MMFC) is proposed and developed to capture multiple fracture modes including in-plane shearing fracture, cross-thickness shearing fracture with bending effect and tearing fracture with initial damage. The associated calibration procedure for this criterion is developed. The criterion is implemented in a commercial FEA code and several lab validations are conducted. The results show its promising potential to predict AHSS cracking at large strain conditions.

Advanced High Strength Steels (AHSS) have been implemented in the automotive industry to balance the requirements for vehicle crash safety, emissions, and fuel economy. With lower ductility compared to conventional steels, the fracture behavior of AHSS components has to be considered in vehicle crash simulations to achieve a reliable crashworthiness prediction. Without considering the fracture behavior, component fracture cannot be predicted and subsequently the crash energy absorbed by the fractured component can be over-estimated. In full vehicle simulations, failure to predict component fracture sometimes leads to less predicted intrusion. In this paper, the feasibility of using computer simulations in predicting fracture during crash deformation is studied.

Continuous efforts to develop a lightweight alloy suitable for the most demanding applications in automotive industry resulted in a number of advanced aluminum (Al) and magnesium alloys and manufacturing routes. One example of this is the application of 319 Al alloy for production of 3.6L V6 gasoline engine blocks. Aluminum is sand cast around Fe-liner cylinder inserts, prior to undergoing the T7 heat treatment process. One of the critical factors determining the quality of the final product is the type, level, and profile of residual stresses along the Fe liners (or extent of liner distortion) that are always present in a cast component. In this study, neutron diffraction was used to characterize residual stresses along the Al and the Fe liners in the web region of the cast engine block. The strains were measured both in Al and Fe in hoop, radial, and axial orientations. The stresses were subsequently determined using generalized Hooke's law.

Scuffing is a common source of failure for many mechanical components in automobiles. 8625 alloy steel is commonly used in camshafts, gears, piston pins, shafts, and splines. The purpose of the research is to study the scuffing resistance of non-treated, carburized, nitrocarburized, and carbonitrided 8625 alloy steels. The scuffing resistance of the 8625 alloy steels was determined through pin-on-disk tests. The hardness and microstructure of the disks were analyzed using electron microscopy to determine wear mechanisms for each surface treated steel. The wear mechanisms were then related to the scuff resistance of the various materials.

Neutron diffraction is a powerful tool that can be used to identify the phases present and to measure the spacing of the atomic planes in a material. Thus, the residual stresses can be determined within a component and/or the phases present. New intercritically austempered irons rely on the unique properties of the austenite phase present in their microstructures. If these materials are to see widespread use, methods to verify the quality (behavior consistency) of these materials and to provide guidance for further optimization will be needed. Neutron diffraction studies were performed at the second generation neutron residual stress facility (NRSF2) at the High Flux Isotope Reactor (HFIR) at Oak Ridge National Laboratory on a variety of intercritically austempered irons. For similar materials, such as TRIP steels, the strengthening mechanism involves the transformation of metastable austenite to martensite during deformation.

Magnesium and aluminum alloys offer lightweighting opportunities in automotive applications. Joining of dissimilar materials, however, generally requires methods that do not involve fusion. This paper explores the use of self-pierce riveting (SPR) to join magnesium to aluminum alloys for structural and closure applications. The preliminary results indicate that SPR is a viable option for joining aluminum extrusions to magnesium die castings, as well as stamped sheet aluminum to quick-plastic-formed (QPF) sheet magnesium.

This paper will present the results of 3-D finite element analyses of single lap adhesive joints between magnesium and three other automotive materials, namely steel, aluminum and SRIM composites. The modulus of magnesium is lower than that of either steel or aluminum, but is higher than that of SRIM. Thus, this study aims at determining the effect of the difference in substrate modulus on the deformation, stress and strain distributions and maximum stresses in adhesive joints of magnesium with the other three materials. In addition, the effect of adhesive modulus is also explored.

Experimental decklids for the Cadillac STS sedan were made with Al AA5083 sheet outer panels and Mg AZ31B sheet inner panels using regular-production forming processes and hardware. Joining and coating processes were developed to accommodate the unique properties of Mg. Assembled decklids were evaluated for dimensional accuracy, slam durability, and impact response. The assemblies performed very well in these tests. Explicit and implicit finite element simulations of decklids were conducted, and showed that the Al/Mg decklids have good stiffness and strength characteristics. These results suggest the feasibility of using Mg sheet closure panels from a structural perspective.

Organic acid degradation products and other anions in engine oil were speciated by capillary electrophoresis (CE) and liquid chromatography-mass spectrometry (LCMS) with electrospray ionization. The sample preparation procedure involved selectively extracting the acids and other water soluble salts into 0.05M aqueous potassium hydroxide. Samples of engine-aged mineral oil and synthetic engine oil contained formic acid, acetic acid, and complex mixtures of fatty acid degradation products. CE analysis of formic acid, acetic acid and selected fatty acids is proposed as a new chemical analysis method for evaluating the condition of engine oil and for studying the effects of high temperature-high load (HTHL) oxidation. Because the overall pattern of CE peaks in the electropherogram changes with oil age or condition, CE-fingerprint (i.e., pattern recognition) techniques may also be useful for evaluating an aged oil's condition or remaining service life.

Three-point bending under quasi-static loading was carried out on empty and partially foam-filled tubes. ALPORAS® aluminum foam was used as an insert with aluminum alloy tube in the experiment. The experiment was modeled using the finite element (FE) code software package LS-DYNA®. The Deshpande-Fleck constitutive model was implemented in the simulation to model the foam. Its material parameters were calibrated against experimental data. The material parameters for the tube were also derived experimentally. Experimental data showed increase in specific energy absorption of approximately 17% whilst the lowest generator of the tube was found to increase by approximately 14% with inclusion of partially filling foam. The FE simulations compared well with the experiments, with the load-displacement and LG-indenter displacement agreeing within approximately 15%. Visual inspection of the foam showed local densification around the point of indentation.

Al383/SiO₂ metal matrix composites (MMC) were designed to increase the wear properties of the Al alloy. However, the soft Al matrix was subject to large plastic deformation under high normal load during lubricated sliding wear tests, causing detachment of the reinforced particles. To further increase the wear resistance of the MMC, in this research, Plasma Electrolytic Oxidation (PEO) process was used to form oxide coatings on the MMC. The hard and wear-resistant oxide coatings protected the metal matrix during the wear tests, reducing the wear rate of MMC. The effect of both oxide coating thickness and volume content of SiO₂ particles on the wear behavior of MMC was investigated. It was found that with a proper combination of the volume content of SiO₂ and coating thickness, the MMC exhibited high wear resistance and low friction coefficient.

The general manufacturing objective during the fabrication of automotive components, particularly through machining, can be stated as the striving to achieve predefined product quality characteristics within equipment, cost and time constraints. The current state of the economy and the consequent market pressure has forced vehicle manufacturers to simultaneously reduce operating expenses along with further improving product quality. This paper examines the achievability of surface roughness specifications within efforts to reduce automotive component manufacture cycle time, particularly by changing cutting feeds. First, the background and attractiveness of aluminum as a lightweight automotive material is discussed. Following this, the methodologies employed for the prediction of surface roughness in machining are presented. The factors affecting surface roughness as well as practical techniques for its improvement through optimizing machining parameters are discussed next.

In August 2005, National Highway Traffic Safety Administration (NHTSA) proposed to increase the roof strength requirement under Federal Motor Vehicle Safety Standard (FMVSS) 216 from 1.5 to 2.5 times unloaded vehicle weight (UVW). To meet the new requirement with a minimum impact on vehicle weight and cost, the automotive community is working actively to develop improved roof architectures using advanced high strength steels (AHSS) and other lightweight materials such as structural foam. The objective of this study is to develop an optimized steel-only solution with low material and part-manufacturing costs. Since the new regulation will present a particular challenge to the roof architectures of large vans, pickup trucks and SUVs due to their large mass and size, a validated roof crush model on a B-Pillar-less light truck is utilized in this study.