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Toyota is committed to the development of advanced powertrains to help address concerns with future oil supplies, the impacts of increased carbon dioxide emissions, and air pollution. Towards that end Toyota is planning to bring to market in 2012 a plug-in hybrid vehicle, a short range electric vehicle, a long range electric vehicle and in the 2015 timeframe hydrogen powered fuel cell vehicle. This presentation will focus on our electric vehicle plans and the challenges with bringing electric vehicle to the market. From the 2010 Alt Fuels Study, Toyota has identified that two key barriers for EV adoption are the times to charge the vehicle, and electricity cost. The study finds that the current infrastructure could be sufficient for most driving needs but EV drivers will still need to alter their driving habits slightly.

In the pursuit of a sustainable transportation systems, Toyota is considering a comprehensive approach pursuing multiple advanced technologies to address three primary issues: GHG, Petroleum Use, and Air Quality. Vehicles must be ready for and affordable to the mass market to provide the customer choices to meet their transportation needs whether it is EV's, Hybrids, Plug-In Hybrids or Fuel Cell Hydrogen Hybrids. Our studies have shown that EVs have the potential to provide significant improvements in energy utilization especially combined with other advanced technologies. Toyota believes that a combination of these technolgies will provide complementary solution that enables a sustainable transportation system. Presenter Takehito Yokoo, Toyota Motor Corporation

A conceptual project aimed at understanding the fundamental design considerations concerning the implementation of catalyst systems on outboard marine engines was carried out by Mercury Marine, with the support of the California Air Resources Board. In order to keep a reasonable project scope, only electronic fuel injected four-stroke outboards were considered. While they represent a significant portion of the total number of outboard engines sold in the United States, carbureted four-strokes and direct injected two-strokes pose their own sets of design constraints and were considered to be outside the scope of this study. Recently, three-way catalyst based exhaust emissions aftertreatment systems have been introduced into series production on sterndrive and inboard marine spark ignition engines in North America. The integration of catalyst systems on outboards is much more challenging than on these other marine propulsion alternatives.

Papers in this collection focus on particle emissions from combustion engines, including measurement and testing methods, and the effects of changes in fuel composition. Topics of the environmental and health effects of elemental carbon and organic carbon that constitutes solid cored particles, plus the environmental and health effects of secondary organic aerosol emissions, are also addressed. This includes particulate emissions from both gasoline and diesel engines.

Papers included in this collection cover the systems engineering experience required to achieve ultra-low emission levels on gasoline light-duty vehicles. Emission system component topics include the development of advanced three-way catalysts, the development of NOX control strategies for gasoline lean burn engines, the application of high cell density substrates to advanced emission systems, and the integration of these components into full vehicle emission systems.

Papers included in this collection cover the systems engineering experience required to achieve ultra-low emission levels on gasoline light-duty vehicles. Emission system component topics include the development of advanced three-way catalysts, the development of NOX control strategies for gasoline lean burn engines, the application of high cell density substrates to advanced emission systems, and the integration of these components into full vehicle emission systems.

Abstract Vehicle cabin air quality depends on various parameters such as number of passengers, fan speed, and vehicle speed. In addition to controlling the temperature inside the vehicle, HVAC control system has evolved to improve cabin air quality as well. However, there is no standard test method to ensure reliable and repeatable comparison among different cars. The current study defined Cabin Air Quality Index (CAQI) and proposed a test method to determine CAQI. CAQIparticles showed dependence on the choice of metrics among particle number (PN), particle surface area (PS), and particle mass (PM). CAQIparticles is less than 1 while CAQICO2 is larger than 1. The proposed test method is promising but needs further improvement for smaller coefficient of variations (COVs).

Papers in this collection focus on particle emissions from combustion engines, including measurement and testing methods, and the effects of changes in fuel composition. Topics of the environmental and health effects of elemental carbon and organic carbon that constitutes solid cored particles, plus the environmental and health effects of secondary organic aerosol emissions, are also addressed. This includes particulate emissions from both gasoline and diesel engines.

EPA's 2007 Diesel particulate matter (DPM) standard requires a large reduction in total mass emissions. In practice, this amounts to a fractional reduction in elemental carbon emissions. The reduction is balanced by a fractional increase in the semi-volatile component, which is difficult to sample and quantify accurately at low concentrations using filter-based methods. In this work, we show how five imprecisely defined filter-sampling parameters influence the mass collected on a filter. These parameters are: dilution air quality, dilution conditions (dilution ratio and dilution air temperature), particle size classification, filter media and artifacts, and face velocity. Each factor has the potential to change the mass collected by a minimum of 5% of the standard, suggesting there is room for improvement.

Ethanol has been gaining attention as a partial substitute in North American pump gasoline in amounts up to 85% ethanol and 15% gasoline, or what is commonly known as “E85”. The problems with E85 fuel for cold start emissions relative to gasoline fuel are the lower energy density and vapor pressure for combustion. Each contributes to excess E85 fuel injected during cold start for comparable combustion quality and drivability to gasoline. The excess emissions occur before the first three-way catalyst (TWC) converter is warmed-up and active for engine-out exhaust conversion. The treatment of non-methane organic gas (NMOG) emissions from the combustion of E85 and gasoline was evaluated using several different zeolite based hydrocarbon (HC) traps coated with different precious metal loadings and ratios. These catalyzed HC traps were evaluated in a flow reactor and also on a gasoline Partial Zero Emissions Vehicle (PZEV) with experimental flexible fuel capability.

The study measured Mass Air Flow, (MAF), Manifold Absolute Pressure, (MAP), and emissions of NO and soot during fourteen transients of speed and load, representative of the Extra Urban Drive Cycle (EUDC). The tests were conducted on a typical passenger car/light-duty truck powertrain (a turbocharged common-rail diesel engine, of in-line 4-cylinder configuration). The objective was to compare NO and soot with corresponding steady-state emission results and propose an engine measurement methodology that will potentially quantify deviation (i.e. deterioration with respect to steady state optimum) in emissions of NO and soot during transients. Comparison between steady state, quasi-steady-states (defined later in the paper) and transients indicated that discrete quasi-steady-state engine operation, can be used for accurate prediction of transient emissions of NO and soot.

Prior technical work by various OEMs and lubricant formulators has identified lubricant-derived phosphorus as a key element capable of significantly reducing the efficiency of modern emissions control systems of gasoline-powered vehicles ( 1 , 2 , 3 , 4 , 5 , 6 , 7 , 8 , 9 , 10 , 11 , 12 , 13 ). However, measuring the exact magnitude of the detriment is not simple or straightforward exercise due to the many other sources of variation which occur as a vehicle is driven and the catalyst is aged ( 1 ). This paper, the second one in the series of publications, examines quantitative sets of results generated using various vehicle and exhaust catalyst testing methodologies designed to follow the path of lubricant-derived phosphorous transfer from oil sump to exhaust catalytic systems ( 1 ).

A simultaneous multi-composition analyzing (SMCA) resonance enhanced multi-photon ionization (REMPI) system was used to investigate gasoline engine exhaust. Observed peaks for exhaust were smaller mass numbers than those from diesel exhaust. However, large species up to three ring aromatics were observed suggesting that soot precursor forms even in the gasoline engine. At low catalyst temperature condition, the reduction efficiencies of a three-way catalyst were higher for higher mass numbers. This result indicates that the larger species accumulate in the catalyst or elsewhere due to their lower vapor pressures. To evaluate the emission of low volatility species, the accumulation should be taken into account. In the hot mode, reduction efficiencies for aromatic species of three-way catalyst were almost 99.5% however, they fall to 70% in the cold start condition.

Two major barriers to wider use of ethanol as an engine fuel are ethanol's low heating value per volume relative to gasoline and higher hydrocarbon emissions at startup. Ethanol provides about one-third lower fuel economy than gasoline on a volumetric basis if the two fuels are utilized with equal efficiency, making ethanol less attractive to consumers. In addition, it is difficult to meet emissions standards such as SULEV when using E85 or hydrous ethanol, because ethanol's low volatility and high heat of vaporization compared to gasoline result in incomplete combustion when the engine is cold. A catalyst consisting of a copper-plated nickel sponge has recently been developed that enables ethanol to be reformed at around 300°C to a mixture of hydrogen (H₂), carbon monoxide (CO), and methane (CH₄). This low reforming temperature enables heat to be supplied from the engine exhaust.

This paper deals with experimental study of in-cylinder tumble flows in a single-cylinder, four-stroke, two-valve internal combustion engine using a pentroof-offset-bowl piston under non-reacting conditions with four intake manifold orientations at an engine speed of 1000 rev/min., during suction and compression strokes using particle image velocimetry. Two-dimensional in-cylinder tumble flow measurements and analysis are carried out in combustion space on a vertical plane passing through cylinder axis. Ensemble average velocity vectors are used to analyze the tumble flows. Tumble ratio (TR) and average turbulent kinetic energy (TKE) are evaluated and used to characterize the tumble flows. From analysis of results, it is found that at end of compression stroke, 90° intake manifold orientation shows an improvement in TR and TKE compared other intake manifold orientations considered.

Gasoline turbocharged direct injection (GTDI) engines, such as EcoBoost™ from Ford, are becoming established as a high value technology solution to improve passenger car and light truck fuel economy. Due to their high specific performance and excellent low-speed torque, improved fuel economy can be realized due to downsizing and downspeeding without sacrificing performance and driveability while meeting the most stringent future emissions standards with an inexpensive three-way catalyst. A logical and synergistic extension of the EcoBoost™ strategy is the use of E85 (approximately 85% ethanol and 15% gasoline) for knock mitigation. Direct injection of E85 is very effective in suppressing knock due to ethanol's high heat of vaporization - which increases the charge cooling benefit of direct injection - and inherently high octane rating. As a result, higher boost levels can be achieved while maintaining optimal combustion phasing giving high thermal efficiency.

A Constant Volume Sampler (CVS) over dilutes the exhaust gas sample when testing Plug-In Hybrid Electric Vehicles (PHEV). This is because the CVS continues to fill the sample bag when the engine is shutdown. With a PHEV, it is possible to complete an FTP test with the engine running less than 20% of the time, resulting in a CVS bag dilution ratio in the range of 100 to 300. The CVS dilution ratio should be in the range of 5-25 for accurate results. At higher dilution ratios, the gas concentrations of CO, NOx and THC approach the ambient background level in the test cell. At a dilution of 100, the CO₂ concentration in the sample bag is about 0.13%, which is only 3 times the air background concentration. The measurement errors caused by over dilution create errors of 10% to 30% in the calculated mass of CO₂, CO, and NOx. Estimated errors for THC are in the range of 200%.

A dilute spark-ignited engine concept has been developed as a potential low cost competitor to diesel engines by Southwest Research Institute (SwRI), with a goal of diesel-like efficiency and torque for light- and medium-duty applications and low-cost aftertreatment. The targeted aftertreatment method is a traditional three-way catalyst, which offers both an efficiency and cost advantage over typical diesel aftertreatment systems. High levels of exhaust gas recirculation (EGR) have been realized using advanced ignition systems and improved combustion, with significant improvements in emissions, efficiency, and torque resulting from using high levels of EGR. The primary motivation for this work was to understand the impact high levels of EGR would have on particulate matter (PM) formation in a port fuel injected (PFI) engine. While there are no proposed regulations for PFI engine PM levels, the potential exists for future regulations, both on a size and mass basis.

Prior work by various OEMs has identified the ability of phosphorus-containing compounds to interfere with the efficiency of modern emissions control systems utilized by gasoline-powered vehicles. Considering the growing societal concerns about ecological effects of exhaust emissions, greenhouse gas emissions and related global climatic changes, it becomes desirable to examine the effect of reduced phosphorous (P) deposits in various vehicle makes, models and types of service, over the lifetime of a vehicle's operation. This paper assesses advantages and disadvantages of various methods to examine the path of P transfer throughout exhaust catalytic systems. Test types discussed include examples of bench testing focusing on catalyst compatibility, dyno mileage accumulation and field trial examinations.

Because of U.S. EPA regulatory actions and the National Academies National Research Council suggestions for improvements in the U.S. EPA emissions inventory methods, the U.S. EPA' Office of Transportation and Air Quality (OTAQ) has made a concerted effort to develop instrumentation that can measure criteria pollutant emissions during the operation of on-road and off-road vehicles. These instruments are now being used in applications ranging from snowmobiles to on-road passenger cars to trans-Pacific container ships. For the betterment of emissions inventory estimation these on-vehicle instruments have recently been employed to measure time resolved (1 hz) in-use gaseous emissions (CO₂, CO, THC, NO ) and particulate matter mass (with teflon membrane filter) emissions from 29 non-road construction vehicles (model years ranging from 1993 to 2007) over a three year period in various counties in Iowa, Missouri, and Kansas.