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To contribute to knowledge required to meet new emission requirements, relationships between multiple injection parameters, degrees of fuel stratification, combustion events, work output and flame luminosity (indicative of particulate abundance) were experimentally investigated using a single-cylinder optical GDI engine. A tested hypothesis was that advancing portions of the mass injected would enhance the fuel-air mixing and thus reduce flame luminescence. An outward-opening piezo actuated fuel injector capable of multiple injections was used to inject the fuel using different triple injection strategies, with various combinations of late and earlier injections leading to various degrees of fuel stratification. Sprays and combustion events were captured using two high-speed cameras and cylinder pressure measurements.