Search Results

Abstract Automotive-grade high-strength steels are galvanized for improved corrosion resistance. However, selective oxidation of alloying elements during annealing heat-treatment may influence the subsequent zinc (Zn) coating quality. The formation of internal and external oxides depends on the alloy composition, especially the Si/Mn ratio, and the oxygen potential of the annealing atmosphere. In this work, a dual-phase (DP) steel was intercritically annealed with varied fuel-to-air ratios in a direct-fired furnace and then galvanized in a Zn bath with 0.2 wt% Al. The type of internal and external oxides and the interfacial structures between the steel substrate, the Al-Fe-Zn inhibition layer, and the Zn coating were examined by using site-specific focused ion beam (FIB) and transmission electron microscopy (TEM).

In this work a detailed model to simulate the transient behavior of catalytic converters is presented. The model is able to predict the unsteady and reacting flows in the exhaust ducts, by solving the system of conservation equations of mass, momentum, energy and transport of reacting chemical species. The en-gine and the intake system have not been included in the simulation, imposing the measured values of mass flow, gas temperature and chemical composition as a boundary condition at the inlet of the exhaust system. A detailed analysis of the diffusion stage triggering is proposed along with simplifications of the physics, finalized to the reduction of the calculation time. Submodels for water condensation and its following evaporation on the monolith surface have been taken into account as well as oxygen storage promoted by ceria oxides.

This specification covers connector and cable accessory heat shrinkable, electrical insulating, molded components fabricated from various polymer based compositions. These components are intended for use as connector and cable accessory components to provide strain relief, electrical insulation, and environmental sealing.

The International Space Station (ISS) requires advanced life support to continue its mission as a permanently-manned space laboratory and to reduce logistic resupply requirements as the Space Shuttle retires from service. Additionally, as humans reach to explore the moon and Mars, advanced vehicles and extraterrestrial bases will rely on life support systems that feature in-situ resource utilization to minimize launch weight and enhance mission capability. An obvious goal is the development of advanced systems that meet the requirements of both mission scenarios to reduce development costs by deploying common modules. A high pressure oxygen generating assembly (HPOGA) utilizing a high differential pressure (HDP) water electrolysis cell stack can provide a recharge capability for the high pressure oxygen storage tanks on-board the ISS independently of the Space Shuttle as well as offer a pathway for advanced life support equipment for future manned space exploration missions.

A growing body of evidence supports an ancient Mars having a milder, wetter climate, suggesting that its atmosphere was once more substantial than it is today. The fate of the lost atmosphere and water is a major unanswered question. Is the “lost” water sequestered in the crust at all latitudes, or did much of it escape to space? While available measurements and theoretical studies suggest that a number of atmospheric escape processes are at work today, little is known about their efficacy, including temporal variations driven by the solar cycle and Mars seasons. Selected 3-D simulations are presented and illustrate the coupling between the thermosphere-ionosphere system and the exosphere leading to predictions of the oxygen corona and hot oxygen escape (a major component of atmospheric loss for present day Mars).

The Moon is composed of a variety of oxygen-bearing minerals, providing a virtually unlimited quantity of raw material that can be processed to produce oxygen. One attractive method to extract oxygen from the lunar regolith is the carbothermal reduction process. This paper discusses recent development work conducted through the PILOT project under the NASA OPTIMA program. The OPTIMA test program utilizes a modular technology suite of ISRU excavation, oxygen extraction, oxygen storage, and oxygen distribution hardware sized to be consistent with the draft Constellation requirements for oxygen extraction from the regolith to support the early lunar outpost (1 MT O2/year).

In support of the Constellation Program, NASA conducted an analysis of crew clothing and laundry options. Disposable clothing is currently used in human space missions. However, the new mission duration, goals, launch penalties and habitat environments may lead to a different conclusion. Mass and volume for disposable clothing are major penalties in long-duration human missions. Equivalent System Mass (ESM) of crew clothing and hygiene towels was estimated at about 11% of total life support system ESM for a 4-crew, 10-year Lunar Outpost mission. Ways to lessen this penalty include: reduce clothing supply mass through using clothes made of advanced fabrics, reduce daily usage rate by extending wear duration and employing a laundry with reusable clothing. Lunar habitat atmosphere pressure and therefore oxygen volume percentage will be different from Space Station or Shuttle. Thus flammability of clothing must be revisited.

Diesel engines with relatively good fuel economy are known as an effective means of reducing CO₂ emissions. It is expected that diesel engines will continue to expand as efforts to slow global warming are intensified. Diesel particulate and NOx reduction system (DPNR), which was first developed in 2003 for introduction in the Japanese and European markets, shows high purification performance which can meet more stringent regulations in the future. However, it is poisoned by sulfur components in exhaust gas derived from fuel and lubricant. We then developed the sulfur trap DPNR with a sulfur trap catalyst that traps sulfur components in the exhaust gas. High purification performance could be achieved with a small amount of platinum group metal (PGM) due to prevention of sulfur poisoning and thermal deterioration.

The Engine Combustion Network (ECN) is becoming a leading group concerning the experimental and computational analysis of Engine combustion. In order to establish a coherent database for model validation, all the institutions participating to the experimental effort carry out experiments at well-defined standard conditions (in particular at Spray A conditions: 22.8kg/m3, 900K, 0% and 15% O2) and with Diesel injectors having the same specifications. Due to the rising number of ECN participants and also to unavoidable damages, additional injectors are required. This raises the question of injector's characteristics reproducibility and of the appropriate method to introduce such new injectors in the ECN network. In order to investigate this issue, a set of 8 new injectors with identical nominal Spray A specification were purchased and 4 of them were characterized using ECN standard diagnostics.

Human rated space vehicles must provide safe breathing air to the crew, in the event of fire or other upset that affects air quality. In very short missions, like those in Mercury, the crew could remain in their flight suit. As mission duration increased, some sort of emergency breathing apparatus was used to provide safe breathing air in emergency situations. The Orion vehicle has a unique set of emergency breathing apparatus design challenges: the vehicle is small compared to shuttle and station, the vehicle does not have a pressurized supply of breathing air, the vehicle has a 30% oxygen design limit, no airlocks or alternate habitable volumes, and during lunar missions the crew members need to remain in the vehicle for many hours after an emergency. A filtering respirator shows special promise to address the needs of Orion, but a filtering respirator for combustion products has never been built and qualified for space.

Detailed chemical kinetics is essential for accurate prediction of combustion performance as well as emissions in practical combustion engines. However, implementation of that is challenging. In this work, dynamic adaptive chemistry (DAC) is integrated into large eddy simulations (LES) of an n-heptane spray flame in a constant volume chamber (CVC) with realistic application conditions. DAC accelerates the time integration of the governing ordinary differential equations (ODEs) for chemical kinetics through the use of locally (spatially and temporally) valid skeletal mechanisms. Instantaneous flame structures and global combustion characteristics such as ignition delay time, flame lift-off length (LOL) and emissions are investigated to assess the effect of DAC on LES-DAC results. The study reveals that in LES-DAC simulations, the auto-ignition time and LOL obtain a well agreement with experiment data under different oxygen concentrations.

With the development of world economy, the shortage in the supply of oil energy as well as the greenhouse effect have become a public concern around the world. The application of biodiesel on vehicle transportation has become the focus of development in many countries. Biodiesel, Fatty Acid Methyl Esters (FAME), is made during the process of transesterification of the animal and vegetable oils. Compared with fossil diesel, biodiesel has some characteristics, such as organic acid, higher water saturation, and oxygen content. From the results of the literatures [1] to [5], it showed that biodiesel would cause the inflation of some plastic and flexible products and the corrosion of metal materials. Metal fuel tanks have the characteristics of high flammability, high impact resistance, and good workability and are often used in commercial vehicles. The corrosion of metal materials is a natural chemical change and it can be influenced by the environment.

This work contributes to the understanding of physical mechanisms that control flashback, or more appropriately combustion recession, in diesel sprays. A large dataset, comprising many fuels, injection pressures, ambient temperatures, ambient oxygen concentrations, ambient densities, and nozzle diameters is used to explore experimental trends for the behavior of combustion recession. Then, a reduced-order model, capable of modeling non-reacting and reacting conditions, is used to help interpret the experimental trends. Finally, the reduced-order model is used to predict how a controlled ramp-down rate-of-injection can enhance the likelihood of combustion recession for conditions that would not normally exhibit combustion recession. In general, fuel, ambient conditions, and the end-of-injection transient determine the success or failure of combustion recession.

Negative valve overlap (NVO) is a viable control strategy that enables low-temperature gasoline combustion (LTGC) at low loads. Thermal effects of NVO fueling on main combustion are well understood, but fuel reforming chemistry during NVO has not been extensively studied. The objective of this work is to analyze the impact of global equivalence ratio and available oxidizer on NVO product concentrations. Experiments were performed in a LTGC single-cylinder engine under a sweep of NVO oxygen concentration and NVO fueling rates. Gas sampling at the start and end of the NVO period was performed via a custom dump-valve apparatus with detailed sample speciation by gas chromatography. Single-zone reactor models using detailed chemistry at relevant mixing and thermodynamic conditions were used in parallel to the experiments to evaluate expected yields of partially oxidized species under representative engine time scales.

In this experimental study, an attempt is made to enhance the performance characteristics of diesel fuel with two different natural additives (NA). Borassus Flabelifer (NB1) and Oryza Sativa straws (NB2) were chosen as natural additives. The selected natural additives were milled for 150 hours using a planetary ball mill and their particle sizes ranging from 120 to 125 nm. The milled natural additives were doped into neat diesel using a magnetic stirrer followed by ultrasonication and their stability was ascertained. The presence of high carbon and oxygen content was noted on EDS results of milled powder. The properties of fuel were analyzed as per ASTM standards and it was observed that there was a marginal decrease in calorific value, flash point, and fire point of the fuel.

A high temperature and no oxygen atmosphere fuel reforming has been proposed for the purpose of exergy saving by theoretical analyzing the detailed exergy loss events of combustion process, the correctness and feasibility of this fuel reforming have been verified through experiments. The exergy behaviors of high temperature and no oxygen atmosphere fuel reforming have been extensively studied, and many benefits had been observed including: (1) simplifying the reforming device where catalysts are not necessary; (2) improving the total chemical exergy while effectively converting large moleculae to small moleculae; (3) improving the mixture’s ratio of specific heat that can promote work-extraction; and (4) lengthening the ignition delay that buys time for better mixing process. All of these benefits are conducive to a better organized HCCI combustion that may improve the engine second law efficiency.

The influence of jet-flow and jet-jet interactions on the lift-off length of diesel jets are investigated in an optically accessible heavy-duty diesel engine. High-speed OH chemiluminescence imaging technique is employed to capture the transient evolution of the lift-off length up to its stabilization. The engine is operated at 1200 rpm and at a constant load of 5 bar IMEP. Decreasing the inter-jet spacing shortens the liftoff length of the jet. A strong interaction is also observed between the bulk in-cylinder gas temperature and the inter-jet spacing. The in-cylinder swirl level only has a limited influence on the final lift-off length position. Increasing the inter-jet spacing is found to reduce the magnitude of the cycle-to-cycle variations of the lift-off length.

A central challenge for efficient auto-ignition controlled low-temperature gasoline combustion (LTGC) engines has been achieving the combustion phasing needed to reach stable performance over a wide operating regime. The negative valve overlap (NVO) strategy has been explored as a way to improve combustion stability through a combination of charge heating and altered reactivity via a recompression stroke with a pilot fuel injection. The study objective was to analyze the thermal and chemical effects on NVO-period energy recovery. The analysis leveraged experimental gas sampling results obtained from a single-cylinder LTGC engine along with cylinder pressure measurements and custom data reduction methods used to estimate period thermodynamic properties. The engine was fueled by either iso-octane or ethanol, and operated under sweeps of NVO-period oxygen concentration, injection timing, and fueling rate.

The share of gasoline engines based on direct injection (DI) technology is rapidly growing, to a large extend driven by their improved efficiency and potential to lower CO2 emissions. One downside of these advanced engines are their significantly higher particulate emissions compared to engines based on port fuel injection technologies [1]. Gasoline particulate filters (GPF) are one potential technology path to address the EU6 particulate number regulation for vehicles powered by gasoline DI engines. For the robust design and operation of GPFs it is essential to understand the mechanisms of soot accumulation and oxidation under typical operating conditions. In this paper we will first discuss the use of detailed numerical simulation to describe the soot oxidation in particulate filters under typical gasoline engine operating conditions. Laboratory experiments are used to establish a robust set of soot oxidation kinetics.

Lithium-rich layered oxide, expressed as xLi2MnO3-(1-x) LiMO2 (M = Ni, Co, Mn, etc.), exhibits a high discharge capacity of 200 mAh/g or more and a high discharge voltage at a charge of 4.5 V or more. Some existing reports on cathode materials state that lithium-rich layered oxide is currently the most promising candidate as an active material for high-energy-density lithium-ion cells, but there are few reports on the degradation mechanism. Therefore, this study created a prototype cell using a lithium-rich layered cathode and a graphite anode, and analyzed the degradation mechanism due to charge and discharge. In order to investigate the causes of degradation, changes in the bulk structure and surface structure of the active material were analyzed using high-resolution X-ray diffraction (HRXRD), a transmission electron microscope (TEM), X-ray absorption fine structure (XAFS), and scanning electron microscope/energy dispersive X-ray spectroscopy (SEM-EDX).