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One promising alternative for meeting stringent NOx limits while attaining high engine efficiency in lean-burn operation are NOx storage catalysts (NSC), an established technology in passenger car aftertreatment systems. For this reason, a NSC system for a stationary single-cylinder CHP gas engine with a rated electric power of 5.5 kW comprising series automotive parts was developed. Main aim of the work presented in this paper was maximising NOx conversion performance and determining the overall potential of NSC aftertreatment with regard to min-NOx operation. The experiments showed that both NOx storage and reduction are highly sensitive to exhaust gas temperature and purge time. While NOx adsorption rate peaks at a NSC inlet temperature of around 290 °C, higher temperatures are beneficial for a fast desorption during the regeneration phase. Combining a relatively large catalyst (1.9 l) with a small exhaust gas mass flow leads to a low space velocity inside the NSC.

Fossil fuels such as natural gas used in engines still play the most important role worldwide despite such measures as the German energy transition which however is also exacerbating climate change as a result of carbon dioxide emissions. One way of reducing carbon dioxide emissions is the choice of energy sources and with it a more favourable chemical composition. Natural gas, for instance, which consist mainly of methane, has the highest hydrogen to carbon ratio of all hydrocarbons, which means that carbon dioxide emissions can be reduced by up to 35% when replacing diesel with natural gas. Although natural gas engines show an overall low CO2 and pollutant emissions level, methane slip due to incomplete combustion occurs, causing methane emissions with a more than 20 higher global warming potential than CO2.