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Technical Paper

A Comparison of the Emissions from a Vehicle in Both Normal and Selected Malfunctioning Operation Modes

1996-10-01
961903
A 1990 Ford Taurus operated on reformulated gasoline was tested under three modes of malfunction: disabled heated exhaust gas oxygen (HEGO) sensor, inactive catalytic converter, and controlled misfire. The vehicle was run for four U.S. EPA UDDS driving schedule (FTP-75) tests at each of the malfunction conditions, as well as under normal operating conditions. An extensive set of emissions data were collected. In addition to the regulated emissions (HC, CO, and NOx), a detailed chemical analysis was carried out to determine the gas- and particle-phase non-regulated emissions. The effect of vehicle malfunction on gas phase emissions was significantly greater than it was on particle phase emissions. For example, CO emissions ranged from 2.57 g/mi (normal operation) to 34.77 g/mi (disable HEGO). Total HCs varied from 0.22 g/mi (normal operation) to 2.21 g/mi (blank catalyst). Emissions of air toxics (1,3-butadiene, benzene, acetaldehyde, and formaldehyde) were also significantly effected.
Technical Paper

A Feedback A/F Control System for Low Emission Vehicles

1993-03-01
930388
Recent Federal and California legislation have mandated major improvements in emission control. Tailpipe HC emission must be decreased an order of magnitude for the California Ultra Low Emission Vehicle (ULEV) standard. Present feedback A/F* control systems employ a Heated Exhaust Gas Oxygen sensor (HEGO sensor) upstream of the catalyst to perform A/F feedback control. Limitations on the ultimate accuracy of these switching sensors are well known. To overcome these limitations a linear Universal Exhaust Gas Oxygen sensor (UEGO sensor) placed downstream from the minicatalyst is employed to attain improved A/F control and therefore, higher three-way catalyst (TWC) conversion efficiency. This configuration was granted a patent in 1992 (1**). This study compares performance differences between the two feedback control systems on a Ford Mustang. In initial studies both the UEGO and HEGO sensors were compared at the midposition location downstream of a minicatalyst.
Technical Paper

A Linear Catalyst Temperature Sensor for Exhaust Gas Ignition (EGI) and On Board Diagnostics of Misfire and Catalyst Efficiency

1993-03-01
930938
Afterburning of a rich exhaust/air mixture ahead of the catalyst has been shown in earlier papers to offer an effective means of achieving catalyst light-off in very short times. Protection of the catalyst from overheating is an important aspect of systems using EGI, and on board diagnostics will be required to check for proper function of EGI. In this paper, some options for these requirements are discussed, using a high temperature linear thermistor.
Technical Paper

A New Test for Catalyst Oxygen Storage Which Correlates with Catalyst Performance on the Vehicle

1994-10-01
942071
A new laboratory test for measuring catalyst oxygen storage capacity has been developed. The test accurately predicts catalyst performance on the vehicle during transient A/F excursions and correlates well with vehicle CO and Nox tailpipe emissions. The test was subsequently used to facilitate improved oxygen storage capacity for new Pd-only washcoat formulations.
Technical Paper

A Review of the Dual EGO Sensor Method for OBD-II Catalyst Efficiency Monitoring

1994-10-01
942057
This paper provides an overview of the dual EGO sensor method for OBD-II catalyst efficiency monitoring. The processes governing the relationship between catalyst oxygen storage, HC conversion efficiency, and rear EGO sensor response are reviewed in detail. A simple physical model relating catalyst oxygen storage capacity and rear EGO sensor response is constructed and used in conjunction with experimental data to provide additional insight into the operation of the catalyst monitor. The effect that the catalyst washcoat formulation has in determining the relationship between catalyst oxygen storage capacity and HC conversion efficiency and its impact on the catalyst monitor is also investigated. Lastly, the effects of catalyst failure mode, fuel sulfur, and the fuel additive MMT on the catalyst monitor's ability to properly diagnose catalyst function are discussed.
Technical Paper

A Simplified Approach to Modeling Exhaust System Emissions: SIMTWC

1999-10-25
1999-01-3476
The optimized design of an exhaust emission system in terms of performance, cost, packaging, and engine control strategy will be a key part of competitively meeting future more stringent emission standards. Extensive use of vehicle experiments to evaluate design system tradeoffs is far too time consuming and expensive. Imperative to successfully meeting the challenges of future emission regulations and cost constraints is the development of an exhaust system simulation model which offers the ability to sort through major design alternatives quickly while assisting in the interpretation of experimental data. Previously, detailed catalyst models have been developed which require the specification of intricate kinetic mechanisms to determine overall catalyst performance. While yielding extremely valuable results, these models use complex numerical algorithms to solve multiple partial differential equations which are time consuming and occasionally numerically unstable.
Technical Paper

An Algorithm to Compensate for Air Charge Prediction Errors

2000-03-06
2000-01-0258
Various methods are available to predict future cylinder air charge for improved air/fuel control. However, there can never be perfect prediction. This paper presents an algorithm to correct for imperfect cylinder charge prediction. This is done by expanding the air/fuel control boundary to include the catalyst, and correcting prediction errors as soon as possible using small corrective changes to later cylinder fuel inputs. The method was experimentally tested and showed improved air/fuel control as indicated by reduced variability of catalyst downstream air/fuel ratio. Additional vehicle testing showed potential to further reduce emissions.
Technical Paper

An Urea Lean NOx Catalyst System for Light Duty Diesel Vehicles

1995-10-01
952493
Future European air quality standards for light duty diesel vehicles will include stringent NOx emission regulations. In order to meet these regulations, a lean NOx catalyst system may be necessary. Since the catalytic removal of NOx is very difficult with the large concentration of oxygen present in diesel exhaust, a reductant is usually added to the exhaust to increase the NOx conversion. This paper describes a lean NOx catalyst system for a Transit light-duty truck which uses a reductant solution of urea in water. In this work, a microprocessor was used to vary the amount of the reductant injected depending on the operating conditions of a 2,5 L naturally aspirated HSDI engine. The NOx conversions were 60% and 80% on the current European driving cycle and the U.S. FTP cycles, respectively. Data on the emissions of HC, CO, NOx, particulate mass and composition, individual HC species, aldehydes, PAH and most HC species were evaluated.
Technical Paper

Application of Catalyzed Hydrocarbon Traps to Reduce Hydrocarbon Emissions from Ethanol Flex-Fuel Vehicles

1999-10-25
1999-01-3624
Catalyzed hydrocarbon traps have shown promise in reducing cold-start tailpipe hydrocarbon emissions from gasoline powered vehicles. In this paper, we report the use of catalyzed hydrocarbon trap technology to reduce the non-methane hydrocarbon emissions from a flex-fuel vehicle that can operate on fuel mixtures ranging from pure gasoline to 85% ethanol/15% gasoline. We have found that hydrocarbon traps show a substantially greater reduction in hydrocarbon emissions when used with ethanol fuel than with gasoline. We present laboratory and vehicle test results that show that tailpipe non-methane hydrocarbon emissions from a flex-fuel vehicle can be reduced by 43% when using 85% ethanol/15% gasoline fuel and 16% when using gasoline fuel from a baseline exhaust system using a three-way catalyst. These results were obtained using a catalyzed hydrocarbon trap specifically formulated for use with ethanol fuel.
Journal Article

Blowdown Interference on a V8 Twin-Turbocharged Engine

2011-04-12
2011-01-0337
The exhaust blowdown pulse from each cylinder of a multi-cylinder engine propagates through the exhaust manifold and can affect the in-cylinder pressure of other cylinders which have open exhaust valves. Depending on the firing interval between cylinders connected to the same exhaust manifold, this blowdown interference can affect the exhaust stroke pumping work and the exhaust pressure during overlap, which in turn affects the residual fraction in those cylinders. These blowdown interference effects are much greater for a turbocharged engine than for one which is naturally aspirated because the volume of the exhaust manifolds is minimized to improve turbocharger transient response and because the turbines restrict the flow out of the manifolds. The uneven firing order (intervals of 90°-180°-270°-180°) on each bank of a 90° V8 engine causes the blowdown interference effects to vary dramatically between cylinders.
Technical Paper

Calculating the Rate of Exothermic Energy Release for Catalytic Converter Efficiency Monitoring

1995-10-01
952423
This paper reports on the development of a new methodology for OBD-II catalyst efficiency monitoring. Temperature measurements taken from the center of the catalyst substrate or near the exterior surface of the catalyst brick were used in conjunction with macroscopic energy balances to calculate the instantaneous rate of exothermic energy generation within the catalyst. The total calculated rate of exothermic energy release over the FTP test cycle was within 10% of the actual or theoretical value and provided a good indicator of catalyst light-off for a variety of aged catalytic converters. Normalization of the rate of exothermic energy release in the front section of the converter by the mass flow rate of air inducted through the engine was found to provide a simple yet practical means of monitoring the converter under both FTP and varying types of road driving.
Technical Paper

Cascade Processing of NOx by Two-Step Discharge/Catalyst Reactors

2001-09-24
2001-01-3509
We present here a phenomenological analysis of a cascade of two-step discharge-catalyst reactors. That is, each step of the cascade consists of a discharge reactor in series with a catalyst bed. These reactors are intended for use in the reduction of tailpipe emission of NOx from diesel engines. The discharge oxidizes NO to NO2, and partially oxidizes HC. The NO2 then reacts on the catalyst bed with hydrocarbons and partially oxidized HCs and is reduced to N2. The cascade may be essential because the best catalysts for this purpose that we have also convert significant fractions of the NO2 back to NO. As we show, reprocessing the gas may not only be necessary, but may also result in energy savings and increased device reliability.
Technical Paper

Catalytic Converter Vehicle System Performance: Rapid versus Customer Mileage

1971-02-01
710292
Two types of catalysts were tested in a fleet of twenty-four 1969 vehicles, operated in customer-type urban driving regimes, on both leaded and nonleaded fuels over a period of 18 months. The two catalyst types and the converter systems chosen for this evaluation were selected on the basis of information obtained from an earlier test program involving four cars that were durability tested on a more rapid “test track mileage accumulation cycle.” Comparisons are made between the vehicles running rapid mileage accumulation and the vehicles running slower customer-type mileage accumulation. Catalyst life and system performance depreciation were relatively similar in both fleets and did not seem to be significantly affected by the method of mileage accumulation. The 24-vehicle fleet was equipped with a programmed protection system (PPS) designed to protect the catalysts from damage due to over-temperature operation. Problems with this prototype protection system are discussed.
Technical Paper

Characterization of Automotive Catalysts Exposed to the Fuel Additive MMT

1989-02-01
890582
A series of in-use catalysts having mileage of 22,000 to 43,000 miles was characterized to determine the effect of the fuel additive MMT. The analytical techniques included visual examination, x-ray fluorescence, x-ray diffraction, optical microscopy, scanning electron microscopy, and electron raicroprobe. In addition, catalyst activity was measured and compared to the catalyst activity from a pulsator aged catalyst without the MMT additive in the feed gas composition. Characterization results show a significantly thick layer (5-20 microns) covering the surface of the catalysts which results in the increase of mass transfer resistance. Steady state R and light-off measurements indicated catalyst efficiency is also significantly reduced as exposure to MMT is increased.
Technical Paper

Characterization of Phosphates Found in Vehicle-Aged Exhaust Gas Catalysts: A Raman Study

2006-04-03
2006-01-0410
Phosphorus contamination from engine oil additives has been associated with reduced performance of vehicle-aged exhaust gas catalysts. Identifying phosphorus species on aged catalysts is important for understanding the reasons for catalytic performance degradation. However, phosphorus is present only in small quantities, which makes its detection with bulk analytical techniques difficult. Raman microscopy probes small regions (a few microns in diameter) of a sample, and can detect both crystalline and amorphous materials. It is thus ideal for characterizing phosphates that may have limited distribution in a catalyst. However, suitable Raman spectra for mixed-metal phosphates that might be expected to be present in contaminated catalysts are not generally available.
Technical Paper

Close Coupled Catalyst System Design and ULEV Performance After 1050° C Aging

1995-10-01
952415
Close coupled catalysts represent a solution being pursued by automotive engineers to meet stringent LEV and ULEV emission standards. Close coupled systems provide fast light-off by utilizing the energy in the exhaust gas rather than energy supplied by an auxiliary source such as an electrically heated catalyst or a burner in the exhaust. Previous close coupled catalyst designs were limited by the temperature capability of the catalyst coatings. A successful close coupled catalyst technology has been developed 'that is resistant to higher temperature deactivation. This technology is able to function well at low temperature during the vehicle cold start when light-off is critical. The close coupled catalyst technology has approached ULEV emission levels after aging at 1050°C for 24 hours. This study will present experimental results for a close coupled catalyst including the selection of catalyst volume, cross sectional area and combination of catalyst technologies.
Technical Paper

Correlation of Exhaust Valve Temperatures with Engine Reynolds Number in a 1.9 L Engine

1992-02-01
920063
Exhaust valve temperatures are important in the selection of valve materials, and have strong effects on borderline spark angle and pre-ignition borderline limit. In order to support analytical modeling of exhaust valve temperatures and to correlate exhaust valve temperatures as a function of engine Reynolds number, exhaust valve temperatures were mapped as a function of spark angle and engine coolant temperatures at 2000 rpm. In addition temperatures were measured at wide open throttle at 2000, 3000, and 4000 rpm. The exhaust valve temperature was expressed as a dimensionless temperature using the exhaust gas temperature and the engine coolant temperature, then the dimensionless temperature was correlated as a function of spark angle and engine Reynolds number. The results indicate that once the temperature is known at a given speed and load condition for any one cylinder, the temperature at other speed and load conditions can be reasonably estimated.
Technical Paper

Deactivation of Cu/Zeolite SCR Catalyst under Lean-Rich Aging Conditions

2010-04-12
2010-01-1180
A lean-rich hydrothermal aging was used to study the deactivation of Cu-zeolite SCR catalyst that has enhanced stability. Impact of DOC upstream on the SCR catalyst during the lean-rich aging was also investigated. The LR hydrothermal aging was conducted with the presence of hydrocarbon, CO and H₂ at different O₂ levels. It was found that the SCR catalyst was active for the oxidation of CO, H₂ and hydrocarbon, resulting in significant exotherm across the catalyst. In addition to hydrothermal aging, reductive aging, especially the presence of H₂ in the aging gas stream without O₂ presence during the L-R aging, might also contribute to the Cu/zeolite SCR catalyst deactivation. The impacts of DOC upstream on Cu/zeolite SCR catalysts depended on the aging temperatures. At lower aging temperature, the uncompleted oxidation of hydrocarbon and CO on the DOC might cause steam reforming and water-gas shift reactions on the DOC to form reductive gas stream.
Technical Paper

Design Considerations for Natural Gas Vehicle Catalytic Converters

1993-11-01
933036
Bench reactor experiments were carried out to investigate the effects of operating temperature, precious metal loading, space velocity, and air-fuel (A/F) ratio on the performance of palladium (Pd) catalysts under simulated natural gas vehicle (NGV) exhaust conditions. The performance of these catalysts under simulated gasoline vehicle (GV) conditions was also investigated. In the case of simulated NGV exhaust, where methane was used as the prototypical hydrocarbon (HC) species, peak three-way conversion was obtained under richer conditions than required with simulated GV exhaust (propane and propene HC species). Moreover, the hydrocarbon efficiency of the catalyst under simulated NGV exhaust conditions was more sensitive to both A/F ratio and perturbations in A/F ratio than the HC efficiency under GV exhaust conditions.
Technical Paper

Design of an Integral Perforated Manifold, Muffler, and Catalyst

2001-03-05
2001-01-0222
The development of an integrated Perforated Manifold, Muffler, and Catalyst (PMMC) for an automotive engine exhaust system is described. The design aims to reduce tailpipe emissions and improve engine power while maintaining low sound output levels from the exhaust. The initial design, based on simplified acoustic and fluid dynamic considerations, is further refined through the use of a computational approach and bench tests. A final prototype is fabricated and evaluated using fired engine dynamometer experiments. The results confirm earlier analytical estimates for improved engine power and reductions of emissions and noise levels.
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